Epoxy-Based Nanocomposites Reinforced with New Amino Functionalized Multi-Walled Carbon Nanotubes

被引：24
作者：
Damian, C. M. [1 ]
Pandele, A. M. [1 ]
Andronescu, C. [1 ]
Ghebaur, A. [1 ]
Garea, S. A. [1 ]
Iovu, H. [1 ]
机构：
[1] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Dept Polymer Sci & Technol, Bucharest 010072, Romania
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2011年 / 19卷 / 03期
关键词：
Functionalization; Carbon nanotube; Epoxy resin; Nanocomposite; THERMAL-PROPERTIES; COMPOSITES; MATRIX; DISPERSION;
D O I：
10.1080/15363831003721773
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The aim of the work was to synthesize epoxy-based nanocomposites reinforced with multi-walled carbon nanotubes (MWNT). MWNTs were first functionalized in order to increase the dispersion degree within the polymer matrix and thus to ensure good adhesion between the two components. The functionalization process consists of two steps: first, MWNT were oxidized, and then an amidation reaction occurred with various amines using carbondiimide and succinimide as activators. Thus, new modified MWNT with benzylamine (BA) and nonylphenoxy polypropyleneoxyamine (B100) were synthesized. The nanocomposites obtained were based on diglycidyl ether of bisphenol A (DGEBA) and modified MWNT and were fully characterized by TGA, DMA, XPS, SEM, TEM, and FTIR.
引用
收藏
页码：197 / 209
页数：13
相关论文
共 18 条
[1]   A perspective on combining molecular nanomagnets and carbon nanotube electronics [J].
Bogani, Lapo ;
Wernsdorfer, W. .
INORGANICA CHIMICA ACTA, 2008, 361 (14-15) :3807-3819
[2]   Multiwalled carbon nanotubes grafted with polyhedral oligomeric silsesquioxane and its dispersion in poly(L-lactide) matrix [J].
Chen, Guang-Xin ;
Shimizu, Hiroshi .
POLYMER, 2008, 49 (04) :943-951
[3]   Mechanical and thermal properties of epoxy nanocomposites reinforced with amino-functionalized multi-walled carbon nanotubes [J].
Chen, Xianhong ;
Wang, Jianfeng ;
Lin, Ming ;
Zhong, Wenbin ;
Feng, Tao ;
Chen, Xiaohua ;
Chen, Jianghua ;
Xue, Feng .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 492 (1-2) :236-242
[4]   The reinforcement role of carbon nanotubes in epoxy composites with different matrix stiffness [J].
Ci, LJ ;
Bai, JC .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (3-4) :599-603
[5]   Chemical oxidation of multiwalled carbon nanotubes [J].
Datsyuk, V. ;
Kalyva, M. ;
Papagelis, K. ;
Parthenios, J. ;
Tasis, D. ;
Siokou, A. ;
Kallitsis, I. ;
Galiotis, C. .
CARBON, 2008, 46 (06) :833-840
[6]   XPS photoemission in carbonaceous materials: A "defect" peak beside the graphitic asymmetric peak [J].
Estrade-Szwarckopf, H .
CARBON, 2004, 42 (8-9) :1713-1721
[7]   Characterization of orientation state of carbon nanotubes in shear flow [J].
Fan, ZH ;
Advani, SG .
POLYMER, 2005, 46 (14) :5232-5240
[8]   Fabrication and mechanical/conductive properties of multi-walled carbon nanotube (MVNT) reinforced carbon matrix composites [J].
Gao, XQ ;
Liu, L ;
Guo, QG ;
Shi, JL ;
Zhai, GT .
MATERIALS LETTERS, 2005, 59 (24-25) :3062-3065
[9]   Effects of surfactant treatment on mechanical and electrical properties of CNT/epoxy nanocomposites [J].
Geng, Yan ;
Liu, Ming Yang ;
Li, Jing ;
Shi, Xiao Mei ;
Kim, Jang Kyo .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2008, 39 (12) :1876-1883
[10]   Mechanical and barrier properties of epoxy resin filled with multi-walled carbon nanotubes [J].
Guadagno, Liberata ;
Vertuccio, Luigi ;
Sorrentino, Andrea ;
Raimondo, Marialuigia ;
Naddeo, Carlo ;
Vittoria, Vittoria ;
Iannuzzo, Generoso ;
Calvi, Erika ;
Russo, Salvatore .
CARBON, 2009, 47 (10) :2419-2430
12