Methylene blue poly(vinyl chloride) membrane electrode based on the methylene blue tetraphenylborate ion-pair complex and its application to pharmaceutical analysis

被引：0
|
作者：
Wen, ML [1 ]
Chen, X [1 ]
Zhao, YB [1 ]
Wang, CY [1 ]
机构：
[1] Yunnan Univ, Dept Chem, Kunming 650091, Peoples R China
来源：
ANALYTICAL LETTERS | 1998年 / 31卷 / 07期
关键词：
methylene blue; methylene blue plastic membrane electrode; pharmaceutical analysis;
D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A methylene blue (MB) poly (vinyl chloride) membrane electrode based on MBtetraphenylborate (TPB) ion-pair complex is described. The linear response covers the range 1x10(-2) -1x10(-6) mof dm(-3) MB solution, with a slope of 56.5+/-0.5 mv/decade (pH range 3.0-1 0.0). The detection limit is 7.75 x 10(-7) mol dm(-3). The electrode shows' stability, good reproducibility and fast response. Interferences from common inorganic cations and some organic bases are negligible. These characteristics of the electrode enabled it to be used successfully for the determination of MB in injection.
引用
收藏
页码：1121 / 1130
页数：10
相关论文
共 37 条
  • [1] Potentiometric sensor for methylene blue based on methylene blue-silicotungstate ion association and its pharmaceutical applications
    Wen, ML
    Zhao, YB
    Chen, X
    Wang, CY
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 1999, 18 (06) : 957 - 961
  • [2] Ion-selective electrode with a film membrane based on trioctylhydroxybenzenesulfonic acid for determining methylene blue
    Nizhnikova, EV
    Podterob, AP
    JOURNAL OF ANALYTICAL CHEMISTRY, 2005, 60 (01) : 61 - 64
  • [3] Ion-selective electrode with a film membrane based on trioctylhydroxybenzenesulfonic acid for determining Methylene Blue
    E. V. Nizhnikova
    A. P. Podterob
    Journal of Analytical Chemistry, 2005, 60 : 61 - 64
  • [4] Ion-selective electrode with a film membrane based on trioctylhydroxybenzenesulfonic acid for determining methylene blue
    E. V. Nizhnikova
    A. P. Podterob
    Journal of Analytical Chemistry, 2005, 60 (1) : 61 - 64
  • [5] Spectrophotometric determination of methylene blue in biological fluids after ion-pair extraction and evidence of its adsorption on plastic polymers
    BelazDavid, N
    Decosterd, LA
    Appenzeller, M
    Ruetsch, YA
    Chiolero, R
    Buclin, T
    Biollaz, J
    EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 1997, 5 (06) : 335 - 345
  • [6] Optimization of pH and direct imaging conditions of complexed methylene blue sensitized poly(vinyl chloride) films
    Ushamani, M
    Leenadeenja, NG
    Sreekumar, K
    Kartha, CS
    Joseph, R
    BULLETIN OF MATERIALS SCIENCE, 2003, 26 (03) : 343 - 348
  • [7] Optimization of pH and direct imaging conditions of complexed methylene blue sensitized poly(vinyl chloride) films
    M. Ushamani
    N. G. Leenadeenja
    K. Sreekumar
    C. Sudha Kartha
    Rani Joseph
    Bulletin of Materials Science, 2003, 26 : 343 - 348
  • [8] Nafion-methylene blue functional membrane and its application in chemical and biosensing
    Hong, Jun
    Ghourchian, Hedayatollah
    Rezaei-Zarchi, Saeed
    Moosavi-Movahedi, Ali Akbar
    Ahmadian, Shahin
    Saboury, Ali Akbar
    ANALYTICAL LETTERS, 2007, 40 (03) : 483 - 496
  • [9] Electrochemical behavior of theophylline at methylene blue dye modified electrode and its analytical application
    Bukkitgar, Shikandar D.
    Shetti, Nagaraj P.
    MATERIALS TODAY-PROCEEDINGS, 2018, 5 (10) : 21474 - 21481
  • [10] Flow injection analysis of sulphide based on its photoelectrocatalytic oxidation at poly-methylene blue modified glassy carbon electrode
    Dilgin, Yusuf
    Canarslan, Seda
    Ayyildiz, Onder
    Ertek, Bensu
    Nisli, Gurel
    ELECTROCHIMICA ACTA, 2012, 66 : 173 - 179
1234