New insights in the structural and morphological properties of sol-gel deposited ZnO multilayer films

被引：16

作者：

Demes, T. ^{[1
,2
]}

Ternon, C. ^{[1
,3
]}

Riassetto, D. ^{[1
,2
]}

Roussel, H. ^{[1
,2
]}

Rapenne, L. ^{[1
,2
]}

Gelard, I. ^{[1
,2
]}

Jimenez, C. ^{[1
,2
]}

Stambouli, V. ^{[1
,2
]}

Langlet, M. ^{[1
,2
]}

机构：

[1] Univ Grenoble Alpes, LMGP, F-38000 Grenoble, France

[2] CNRS, LMGP, F-38000 Grenoble, France

[3] Univ Grenoble Alpes, LTM, F-38000 Grenoble, France

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2016年 / 95卷

关键词：

Nanostructures; Thin films; Sol-gel growth; Microstructure; Surface properties; THIN-FILMS; PREFERRED ORIENTATION; NANOWIRE ARRAYS; SEED-LAYER; GROWTH;

D O I：

10.1016/j.jpcs.2016.03.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study shows how the structural and morphological properties of sol-gel deposited ZnO films can be precisely tuned and selectively controlled. For that purpose, ZnO films have been deposited through a multilayer sol-gel route using solutions of zinc acetate dihydrate (ZAD) diluted in 1-butanol. The optogeometrical, morphological, and structural properties of these films have been thoroughly studied in relation to the ZAD concentration in butanol, number of deposited single-layers, and heat-treatment conditions. On this basis, different physical processes occurring over the multilayer deposition procedure have been discussed to explain how the experimental parameters influence the film properties and enable to tune the grain size, texture coefficient, and surface coverage rate in a wide range of values. This work is a first step toward the optimized growth of ZnO nanowires on sol-gel films and their subsequent integration in 2D or 3D nanowire-based biosensors. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：43 / 55

页数：13

共 28 条

[11] Texture development of non-epitaxial polycrystalline ZnO films [J].

Kajikawa, Y .

JOURNAL OF CRYSTAL GROWTH, 2006, 289 (01) :387-394

[12]

Klug H.P., 1974, XRAY DIFFRACTION PRO, V2nd, P992

[13] Zinc Oxide-From Synthesis to Application: A Review [J].

Kolodziejczak-Radzimska, Agnieszka ;

Jesionowski, Teofil .

MATERIALS, 2014, 7 (04) :2833-2881

[14] Electrical and optical properties of ZnO transparent conducting films by the sol-gel method [J].

Lee, JH ;

Ko, KH ;

Park, BO .

JOURNAL OF CRYSTAL GROWTH, 2003, 247 (1-2) :119-125

[15] Ultrathin seed-layer for tuning density of ZnO nanowire arrays and their field emission characteristics [J].

Liu, Jun ;

She, Juncong ;

Deng, Shaozhi ;

Chen, Jun ;

Xu, Ningsheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (31) :11685-11690

[16] Extraction of optical constants of zinc oxide thin films by ellipsometry with various models [J].

Liu, YC ;

Hsieh, JH ;

Tung, SK .

THIN SOLID FILMS, 2006, 510 (1-2) :32-38

[17] Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution [J].

Ohyama, M ;

Kozuka, H ;

Yoko, T .

THIN SOLID FILMS, 1997, 306 (01) :78-85

[18] Preparation of ZnO films with preferential orientation by sol-gel method [J].

Ohyama, M ;

Kozuka, H ;

Yoko, T ;

Sakka, S .

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1996, 104 (04) :296-300

[19] PREPARATION OF N-ZNO/P-SI HETEROJUNCTION BY SOL-GEL PROCESS [J].

OKAMURA, T ;

SEKI, Y ;

NAGAKARI, S ;

OKUSHI, H .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1992, 31 (6B) :L762-L764

[20] JUNCTION PROPERTIES AND GAP STATES OF ZNO THIN-FILM PREPARED BY SOL-GEL PROCESS [J].

OKAMURA, T ;

SEKI, Y ;

NAGAKARI, S ;

OKUSHI, H .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1992, 31 (9B) :3218-3220

← 1 2 3 →