New insights in the structural and morphological properties of sol-gel deposited ZnO multilayer films

被引：16

作者：

Demes, T. ^{[1
,2
]}

Ternon, C. ^{[1
,3
]}

Riassetto, D. ^{[1
,2
]}

Roussel, H. ^{[1
,2
]}

Rapenne, L. ^{[1
,2
]}

Gelard, I. ^{[1
,2
]}

Jimenez, C. ^{[1
,2
]}

Stambouli, V. ^{[1
,2
]}

Langlet, M. ^{[1
,2
]}

机构：

[1] Univ Grenoble Alpes, LMGP, F-38000 Grenoble, France

[2] CNRS, LMGP, F-38000 Grenoble, France

[3] Univ Grenoble Alpes, LTM, F-38000 Grenoble, France

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2016年 / 95卷

关键词：

Nanostructures; Thin films; Sol-gel growth; Microstructure; Surface properties; THIN-FILMS; PREFERRED ORIENTATION; NANOWIRE ARRAYS; SEED-LAYER; GROWTH;

D O I：

10.1016/j.jpcs.2016.03.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study shows how the structural and morphological properties of sol-gel deposited ZnO films can be precisely tuned and selectively controlled. For that purpose, ZnO films have been deposited through a multilayer sol-gel route using solutions of zinc acetate dihydrate (ZAD) diluted in 1-butanol. The optogeometrical, morphological, and structural properties of these films have been thoroughly studied in relation to the ZAD concentration in butanol, number of deposited single-layers, and heat-treatment conditions. On this basis, different physical processes occurring over the multilayer deposition procedure have been discussed to explain how the experimental parameters influence the film properties and enable to tune the grain size, texture coefficient, and surface coverage rate in a wide range of values. This work is a first step toward the optimized growth of ZnO nanowires on sol-gel films and their subsequent integration in 2D or 3D nanowire-based biosensors. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：43 / 55

页数：13

共 28 条

[1] The synthesis of zinc oxide nanoparticles from zinc acetylacetonate hydrate and 1-butanol or isobutanol [J].

Ambrozic, Gabriela ;

Skapin, Sreco D. ;

Zigon, Majda ;

Orel, Zorica Crnjak .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 346 (02) :317-323

[2] Synthesis and characterization of ZnO nanowires and their integration into dye-sensitized solar cells [J].

Baxter, J. B. ;

Walker, A. M. ;

van Ommering, K. ;

Aydil, E. S. .

NANOTECHNOLOGY, 2006, 17 (11) :S304-S312

[3] Transport Limited Growth of Zinc Oxide Nanowires [J].

Boercker, Janice E. ;

Schmidt, Jillian B. ;

Aydil, Eray S. .

CRYSTAL GROWTH & DESIGN, 2009, 9 (06) :2783-2789

[4] Review of hydrothermal ZnO nanowires: Toward FET applications [J].

Burke-Govey, Conor P. ;

Plank, Natalie O. V. .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2013, 31 (06)

[5]

Coleman VA, 2006, ZINC OXIDE BULK, THIN FILMS AND NANOSTRUCTURES: PROCESSING, PROPERTIES AND APPLICATIONS, P1, DOI 10.1016/B978-008044722-3/50001-4

[6] Crystallization behavior and origin of c-axis orientation in sol-gel-derived ZnO:Li thin films on glass substrates [J].

Fujihara, S ;

Sasaki, C ;

Kimura, T .

APPLIED SURFACE SCIENCE, 2001, 180 (3-4) :341-350

[7] General route to vertical ZnO nanowire arrays using textured ZnO seeds [J].

Greene, LE ;

Law, M ;

Tan, DH ;

Montano, M ;

Goldberger, J ;

Somorjai, G ;

Yang, PD .

NANO LETTERS, 2005, 5 (07) :1231-1236

[8]

HARRIS GB, 1952, PHILOS MAG, V43, P113

[9] Sol-gel and ultrafine particle formation via dielectric tuning of inorganic salt-alcohol-water solutions [J].

Hu, MZC ;

Payzant, EA ;

Byers, CH .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 222 (01) :20-36

[10] Influence of solvent on the growth of ZnO nanoparticles [J].

Hu, ZS ;

Oskam, G ;

Searson, PC .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 263 (02) :454-460

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