Sulfur dioxide gas sensor based on Al3+ and O2- ion conducting solids with gadolinium oxysulfate based auxiliary sensing electrode

被引:5
作者
Inaba, Yuichi [1 ]
Nagai, Tsukasa [1 ]
Tamura, Shinji [1 ]
Imanaka, Nobuhito [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
关键词
gas sensor; sulfur dioxide; solid electrolyte; rare earth oxysulfate;
D O I
10.1166/sl.2008.065
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new solid electrolyte type sulfur dioxide gas sensor was fabricated by the combination of trivalent aluminum cation conducting (Al0.2Zr0.8)(20/19)Nb(PO4)(3) solid and divalent oxide anion conducting yttria stabilized zirconia (YSZ) with 0.8Gd(2)O(2)SO(4)-0.2NaAl(SO4)(2) as an auxiliary sensing electrode. Since the present sensor showed such a superior sensing performance of continuous and rapid response and also showed a linear relationship between the sensor EMF output and the logarithm of the SO2 gas concentration with obeying the theoretical Nernst relationship, it is greatly expected to be a practical SO2 gas sensing device.
引用
收藏
页码:458 / 461
页数:4
相关论文
共 13 条
[1]   GAS-SENSING USING A CHARGE-FLOW TRANSISTOR [J].
BARKER, PS ;
DIBARTOLOMEO, C ;
MONKMAN, AP ;
PETTY, MC ;
PRIDE, R .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 25 (1-3) :451-453
[2]   Amperometric SO2 gas sensors based on solid polymer electrolytes [J].
Chiou, CY ;
Chou, TC .
SENSORS AND ACTUATORS B-CHEMICAL, 2002, 87 (01) :1-7
[3]   Sensor system for indoor air monitoring using semiconducting metal oxides and IR-absorption [J].
Frank, J ;
Meixner, H .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 78 (1-3) :298-302
[4]   SO2 gas sensor based on Al3+ and O2- ion conducting solids with La2O2SO4 auxiliary electrode [J].
Hasegawa, I ;
Hasegawa, Y ;
Imanaka, N .
SENSOR LETTERS, 2005, 3 (01) :27-30
[5]   SODIUM-SULFATE MIXED WITH RARE-EARTH SULFATES(LN=Y AND GD) AND SILICON DIOXIDE AS A SOLID ELECTROLYTE FOR A SULFUR-DIOXIDE DETECTOR [J].
IMANAKA, N ;
YAMAGUCHI, Y ;
ADACHI, G ;
SHIOKAWA, J .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (01) :5-8
[6]   Extraordinary high trivalent Al3+ ion conduction in solids [J].
Imanaka, N ;
Hasegawa, Y ;
Yamaguchi, M ;
Itaya, M ;
Tamura, S ;
Adachi, GY .
CHEMISTRY OF MATERIALS, 2002, 14 (11) :4481-4483
[7]  
IMANAKA N, 2003, ITE LETT, V4, P73
[8]  
IMANAKA N, 2002, ELECTROCHEM SOLID ST, V5, P9
[9]  
INABA Y, SOLID STATE IN PRESS
[10]   Analytical detection system of mixed odor vapors using chemiluminescence-based gas sensor [J].
Nakagawa, M ;
Kawabata, S ;
Nishiyama, K ;
Utsunomiya, K ;
Yamamoto, I ;
Wada, T ;
Yamashita, Y ;
Yamashita, N .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 34 (1-3) :334-338