Efficient hydrodeoxygenation of biomass-derived ketones over bifunctional Pt-polyoxometalate catalyst

被引：58

作者：

Alotaibi, Mshari A. ^{[1
]}

Kozhevnikova, Elena F. ^{[1
]}

Kozhevnikov, Ivan V. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 57期

关键词：

METHYL ISOBUTYL KETONE; HETEROGENEOUS ACID CATALYSIS; ONE-STEP CONVERSION; BUTANOL PRODUCTION; HETEROPOLY ACIDS; MIXED-OXIDE; ACETONE; FERMENTATION; CHEMISTRY;

D O I：

10.1039/c2cc33189f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acidic heteropoly salt Cs2.5H0.5PW12O40 doped with Pt nanoparticles is a highly active and selective catalyst for one-step hydrogenation of methyl isobutyl and diisobutyl ketones to the corresponding alkanes in the gas phase at 100 degrees C with 97-99% yield via metal-acid bifunctional catalysis.

引用

页码：7194 / 7196

页数：3

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