Batteries based on fluoride shuttle

被引：404
作者：
Reddy, M. Anji [1 ]
Fichtner, M. [1 ]
机构：
[1] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 43期
关键词：
RECHARGEABLE LITHIUM BATTERIES; IONIC-CONDUCTIVITY; SOLID ELECTROLYTES; GALVANIC CELL; CRYSTALS; CATHODE; CAF2; LAF3;
D O I：
10.1039/c1jm13535j
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In search of new concepts to build batteries with high energy densities, electrochemical cells based on metal fluorides may be promising. Herein, we report the demonstration of secondary battery cells based on fluoride shuttle. In fluoride ion batteries, fluoride anion acts as charge transfer ion between a metal/metal fluoride pair where it will react with metal or evolve from metal fluoride depending on the flow of current.
引用
收藏
页码：17059 / 17062
页数：4
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