An Efficient Synthesis of Vinyl Sulfones from Alkenes and Aryl Sulfinates

被引：40
作者：
Das, Biswanath [1 ]
Lingaiah, Maram [1 ]
Damodar, Kongara [1 ]
Bhunia, Nisith [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNTHESIS-STUTTGART | 2011年 / 18期
关键词：
vinylsulfone; alkene; aryl sulfinate; synthetic methods; ADDITION REACTIONS; HYDROGENOLYSIS; CHEMISTRY; OLEFINS; ACCESS;
D O I：
10.1055/s-0030-1260142
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Vinyl sulfones have been efficiently synthesized by treatment of alkenes with sodium arene sulfinates using potassium iodide and sodium periodate in the presence of a catalytic amount of acetic acid at room temperature. The products are formed in high yields (87-95%) within 2.5-8 hours.
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收藏
页码：2941 / 2944
页数：4
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