Cobalt decorated nitrogen-doped carbon bowls as efficient electrocatalysts for the oxygen reduction reaction

被引:42
作者
Zhong, Haobin [1 ]
Shi, Changwei [1 ]
Li, Jiantao [1 ]
Yu, Ruohan [1 ]
Yu, Qiang [1 ]
Liu, Haoyun [1 ]
Yao, Yao [1 ]
Wu, Jinsong [1 ]
Zhou, Liang [1 ]
Mai, Liqiang [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
ORGANIC FRAMEWORK; POROUS CARBON; METAL; NANOPARTICLES; SPHERES; NANOFIBERS; PARTICLES; EVOLUTION; ALKALINE; GRAPHENE;
D O I
10.1039/c9cc10036a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cobalt decorated nitrogen-doped carbon bowls (Co@NCB) have been successfully constructed by impregnating bowl-like resin particles with cobalt salt followed by annealing. The cobalt exists in the following two forms in the obtained Co@NCB: Co nanoparticles and CoN4. The Co@NCB outperforms the commercial Pt/C in the oxygen reduction reaction in terms of half-wave potential and stability. When Co@NCB is applied in zinc-air batteries, a high open-circuit voltage, excellent power density, and satisfactory stability are achieved.
引用
收藏
页码:4488 / 4491
页数:4
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