Shape-Stabilized Phase Change Materials Based on Stearic Acid and Mesoporous Hollow SiO2 Microspheres (SA/SiO2) for Thermal Energy Storage

被引：45

作者：

Fan, Shuang ^{[1
]}

Gao, Hongyi ^{[1
]}

Dong, Wenjun ^{[1
]}

Tang, Jia ^{[1
]}

Wang, Jingjing ^{[1
]}

Yang, Mu ^{[1
]}

Wang, Ge ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Beijing Key Lab Funct Mat Mol & Struct Construct, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 14期

基金：

中国国家自然科学基金;

关键词：

Phase change materials; Fatty acids; Mesoporous materials; Thermal energy storage; Materials chemistry; POLYETHYLENE-GLYCOL; GRAPHITE COMPOSITE; IMPREGNATION; FABRICATION; CONDUCTIVITY; PROPERTY; BEHAVIOR; SHELL; CORE;

D O I：

10.1002/ejic.201601380

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The development of solar energy conversion and storage technologies has been attracting considerable attention in recent years. In this paper, a novel shape-stabilized phase change material (SSPCM) based on stearic acid (SA) and mesoporous hollow SiO2 microspheres (SA/SiO2) was synthesized by an impregnating method. The mesoporous silica microspheres with an additional hollow cavity not only provide high loading capacity but also favor the free crystallization of SA, which is confined in the hollow microspheres by interfacial interaction and capillary action. There is no leakage from the obtained SSPCMs even if the temperature exceeds the melting point of SA. The SA/SiO2 PCM with 70 wt.-% of SA exhibits high latent heat (reaching up to 135.3 Jg(-1)), and its related thermal conductivity is 0.56 WmK(-1), which was enhanced by 56% relative to that of pure SA. Moreover, the SA/SiO2 composites show excellent thermal stability, which is beneficial for latent heat thermal energy storage (LHTES).

引用

页码：2138 / 2143

页数：6

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