Bis(2-aminobenzothiazole-κN1)bis(thiocyanato-κN)zinc(II)

被引：6

作者：

Suh, Seung Wook ^{[1
]}

Kim, Chong-Hyeak ^{[2
]}

Kim, Inn Hoe ^{[1
]}

机构：

[1] Konyang Univ, Dept Chem, Nonsan 320711, South Korea

[2] Korea Res Inst Chem Technol, Ctr Chem Anal, Taejon 305600, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

COMPLEXES;

D O I：

10.1107/S1600536809030931

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Zn-II ion in the title complex, [Zn(NCS)(2)(C7H6N2S)(2)], is tetrahedrally coordinated within an N-4 donor set defined by two N atoms of two terminal isothiocyanate ligands and by two heterocyclic N atoms of two different 2-aminobenzothiazole ligands. This arrangement is stabilized by intramolecular N-H center dot center dot center dot N hydrogen bonds. In the crystal structure, molecules are linked through N-H center dot center dot center dot S hydrogen bonds to form a two-dimensional array.

引用

页码：M1054 / U419

页数：11

共 15 条

[1] STRUCTURAL CHARACTERIZATION OF LOW-SPIN IRON(III) COMPLEXES OF OCTAETHYLOXOPORPHYRIN [J].

BALCH, AL ;

NOLL, BC ;

SAFARI, N .

INORGANIC CHEMISTRY, 1993, 32 (13) :2901-2905

[2]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[3]

2-Z

[4] Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[5]

Bruker AXS Inc, 2001, SMART SAINT SADABS

[6] Influence of pseudohalide ions on the molecular structure and magnetic properties of the manganese(II)-bipyrimidine-pseudohalide system [J].

Cortes, R ;

Urtiaga, MK ;

Lezama, L ;

Pizarro, JL ;

Arriortua, MI ;

Rojo, T .

INORGANIC CHEMISTRY, 1997, 36 (22) :5016-5021

[7] NEW ROUTE TO BIMETALLIC IMIDAZOLATE-BRIDGED COMPLEXES .6. STRUCTURAL AND MAGNETIC CONSEQUENCES OF STERIC EFFECTS IN MONONUCLEAR AND DINUCLEAR NICKEL(II) AND COPPER(II) COMPLEXES INVOLVING 4-METHYLIMIDAZOLE AS LIGAND [J].

COSTES, JP ;

DAHAN, F ;

LAURENT, JP .

INORGANIC CHEMISTRY, 1991, 30 (08) :1887-1892

[8]

Iwamoto T., 1996, Comprehensive Supramolecular Chemistry, V6, P643

[9]

Kim CH, 2008, ANAL SCI TECHNOL, V21, P562

[10]

KIM IH, 2001, KOREAN J CRYSTALLOGR, V12, P207

← 1 2 →