Metal-organic frameworks for H2 and CH4 storage: insights on the pore geometry-sorption energetics relationship

被引：34

作者：

Alkordi, Mohamed H. ^{[1
]}

Belmabkhout, Youssef ^{[1
]}

Cairns, Amy ^{[1
]}

Eddaoudi, Mohamed ^{[1
]}

机构：

[1] KAUST, Funct Mat Design Discovery & Dev Res Grp FMD3, Div Phys Sci & Engn, Adv Membranes & Porous Mat Ctr, Thuwal 4700, Saudi Arabia

来源：

IUCRJ | 2017年 / 4卷

关键词：

tailored pore geometry; metal-organic frameworks; MOFs; hydrogen storage; dispersive interactions; SECONDARY BUILDING UNITS; HYDROGEN STORAGE; IMIDAZOLATE FRAMEWORKS; ADSORPTION PROPERTIES; AIR SEPARATION; SOC-MOF; CO2; SIMULATION; CHEMISTRY; BLOCKS;

D O I：

10.1107/S2052252516019060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study aims to assess the possibility of improving H-2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H-2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

引用

页码：131 / 135

页数：5

共 39 条

[11] Hydrogen storage in metal-organic frameworks [J].

Collins, David J. ;

Zhou, Hong-Cai .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160

[12] Hydrogen storage in microporous metal-organic frameworks with exposed metal sites [J].

Dinca, Mircea ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (36) :6766-6779

[13] Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal-organic framework [J].

Dinca, Mircea ;

Han, Won Seok ;

Liu, Yun ;

Dailly, Anne ;

Brown, Craig M. ;

Long, Jeffrey R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (09) :1419-1422

[14] Using molecular simulation to characterise metal-organic frameworks for adsorption applications [J].

Dueren, Tina ;

Bae, Youn-Sang ;

Snurr, Randall Q. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1237-1247

[15] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[16] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[17] Recent advances on simulation and theory of hydrogen storage in metal-organic frameworks and covalent organic frameworks [J].

Han, Sang Soo ;

Mendoza-Cortes, Jose L. ;

Goddard, William A., III .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1460-1476

[18] Zeolite a imidazolate frameworks [J].

Hayashi, Hideki ;

Cote, Adrien P. ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

NATURE MATERIALS, 2007, 6 (07) :501-506

[19] Hydrogen storage in metal-organic frameworks [J].

Hirscher, Michael ;

Panella, Barbara .

SCRIPTA MATERIALIA, 2007, 56 (10) :809-812

[20]

Horcajada P., 2006, ANGEW CHEM, V118, P6120, DOI [DOI 10.1002/ANGE.200601878, 10.1002/ange.200601878]

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