Metal-organic frameworks for H2 and CH4 storage: insights on the pore geometry-sorption energetics relationship

被引：34

作者：

Alkordi, Mohamed H. ^{[1
]}

Belmabkhout, Youssef ^{[1
]}

Cairns, Amy ^{[1
]}

Eddaoudi, Mohamed ^{[1
]}

机构：

[1] KAUST, Funct Mat Design Discovery & Dev Res Grp FMD3, Div Phys Sci & Engn, Adv Membranes & Porous Mat Ctr, Thuwal 4700, Saudi Arabia

来源：

IUCRJ | 2017年 / 4卷

关键词：

tailored pore geometry; metal-organic frameworks; MOFs; hydrogen storage; dispersive interactions; SECONDARY BUILDING UNITS; HYDROGEN STORAGE; IMIDAZOLATE FRAMEWORKS; ADSORPTION PROPERTIES; AIR SEPARATION; SOC-MOF; CO2; SIMULATION; CHEMISTRY; BLOCKS;

D O I：

10.1107/S2052252516019060

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This study aims to assess the possibility of improving H-2 and CH4 binding affinity to the aromatic walls of a designed new Metal-Organic Framework (MOF) through simultaneous dispersive interactions. It is suggested here that desirable H-2 and CH4 storage media at low pressures require narrow uniform pores associated with large surface area, a trade-off that is challenging to achieve.

引用

页码：131 / 135

页数：5

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