A theoretical strategy of pure carbon materials for lightweight and excellent absorption performance

被引:138
作者
Yan, Xu [1 ,2 ]
Huang, Xiaoxiao [1 ,2 ]
Chen, Yanting [1 ]
Liu, Yuhao [1 ]
Xia, Long [3 ]
Zhang, Tao [3 ]
Lin, Haiyan [4 ]
Jia, Dechang [1 ,2 ]
Zhong, Bo [3 ]
Wen, Guangwu [5 ]
Zhou, Yu [1 ,2 ]
机构
[1] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, Key Lab Adv Struct Funct Integrat Mat & Green Mfg, Harbin 150001, Peoples R China
[3] Harbin Inst Technol Weihai, Sch Mat Sci & Engn, Weihai 264009, Peoples R China
[4] China Aerosp Sci & Ind Corp, Aerosp Inst Adv Mat & Proc Technol, Beijing 100074, Peoples R China
[5] Shandong Univ Technol, Sch Mat Sci & Engn, Zibo 255000, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon materials; Ultralight; Relaxation intensity; Electromagnetic wave absorption; DIELECTRIC-PROPERTIES; BROAD-BAND; MICROWAVE-ABSORPTION; COMPOSITE; MICROSPHERES; ATTENUATION; ULTRALIGHT; DISPERSION;
D O I
10.1016/j.carbon.2020.11.044
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Developing the pure carbon materials with ultra-light and excellent electromagnetic wave absorption (EWA) performance that aims to solve signal interference or electromagnetic pollution is highly desirable. However, there still remains a huge challenge that whether the pure carbon materials with excellent conductivity can be used as EWA alone and how the performance can be optimized. Keeping the high conductivity and adjusting the relaxation intensity (De) at the same time are theoretically found to be the effective way to improve the attenuation of electromagnetic wave and obtain better impedance matching. Herein, the key relationship between De and EWA property is proved by theoretical calculation. As the experimental design, the pure carbon absorber, CMF (carbonized melamine foam, the density of 4.34 mg cm(-3)), which holds highly conductivity and appropriate De, exhibits a strong absorption (-57.3 dB) and a wide effective absorption band of 8.32 GHz. It is verified when carbon material possesses excellent conductivity, it is easy to steer the optimized design of De toward improving the impedance matching. Meanwhile, the strategy developed here paves a new way for the design of high conductivity and ultralight EWA materials for the practical applications. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页码:662 / 672
页数:11
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