New methods for the synthesis of oxy-functionalized 1,2,4-trioxanes and 1,2,4-trioxepanes from unsaturated hydroperoxy acetals

被引：24

作者：

Ushigoe, Y

Masuyama, A

Nojima, M

McCullough, KJ

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT CHEM MAT,SUITA,OSAKA 565,JAPAN

[2] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(97)10343-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxy-functionalized 1,2,4-trioxanes or 1,2,4-trioxepanes were produced by either autoxidation of the unsaturated hydroperoxy acetals 1, or the acid-catalyzed cyclization of epoxy hydroperoxides 9 which were readily prepared from 1. By the appropriate choice of cyclization procedure, the structures of the resulting cyclic peroxides could be efficiently controlled. (C) 1997 Elsevier Science Ltd.

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页码：8753 / 8756

页数：4

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