Polyaniline encapsulated microporous polymer beads and their vapor and gas adsorption behavior

被引：4
作者：
Deb, Pramil C. [1 ]
Rajput, Lalit D. [1 ]
Singh, Pravin K. [1 ]
机构：
[1] Naval Mat Res Lab, Adv Mat Dept, MIDC Area, Ambernath 421506, Maharashtra, India
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2007年 / 104卷 / 01期
关键词：
copolymerization; encapsulation; adsorption;
D O I：
10.1002/app.25597
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Styrene-maleic acid copolymer beads and styrene-divinylbenzene beads were encapsulated with polyaniline by insitu oxidative polymerization of aniline. These beads both in unmodified and encapsulated forms were studied for their organic vapor and hydrogen adsorption behavior at 30 degrees C and reduced pressure. Enhanced adsorption of hydrogen to the extent of 4.9 mass % was observed for encapsulated styrene-maleic acid copolymer beads. (c) 2007 Wiley Periodicals, Inc.
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页码：297 / 303
页数：7
相关论文
共 21 条
[1]   Polyaniline doped by a new class of dopants, benzoic acid and substituted benzoic acid: synthesis and characterization [J].
Amarnath, CA ;
Palaniappan, S .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (05) :420-424
[2]   LIQUID-CRYSTALLINE SOLUTIONS OF ELECTRICALLY CONDUCTING POLYANILINE [J].
CAO, Y ;
SMITH, P .
POLYMER, 1993, 34 (15) :3139-3143
[3]   Crosslinked styrene-maleic acid copolymer complexes of some transition metals and their adsorption behavior [J].
Deb, PC ;
Rajput, LD ;
Agrawal, AK ;
Singh, PK ;
Hande, V ;
Sasane, S .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (09) :681-687
[4]   Storage of hydrogen in single-walled carbon nanotubes [J].
Dillon, AC ;
Jones, KM ;
Bekkedahl, TA ;
Kiang, CH ;
Bethune, DS ;
Heben, MJ .
NATURE, 1997, 386 (6623) :377-379
[5]   Highly porous and stable metal-organic frameworks: Structure design and sorption properties [J].
Eddaoudi, M ;
Li, HL ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (07) :1391-1397
[6]   Metal-organic frameworks [J].
James, SL .
CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288
[7]   Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].
Li, H ;
Eddaoudi, M ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 1999, 402 (6759) :276-279
[8]  
Mathew A, 1996, J POLYM SCI POL CHEM, V34, P1605
[9]  
Meinzer R. A., 1994, US Pat., Patent No. [5,360,461, 5360461]
[10]   Hydrogen storage using physisorption - materials demands [J].
Nijkamp, MG ;
Raaymakers, JEMJ ;
van Dillen, AJ ;
de Jong, KP .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2001, 72 (05) :619-623
123