Versatile Applications of Metal Single-Atom @ 2D Material Nanoplatforms

被引:168
作者
Zhang, Bin [1 ,2 ]
Fan, Taojian [1 ]
Xie, Ni [2 ]
Nie, Guohui [2 ]
Zhang, Han [1 ]
机构
[1] Shenzhen Univ, SZU NUS Collaborat Innovat Ctr Optoelect Sci & Te, Int Collaborat Lab 2D Mat Optoelect Sci & Technol, Minist Educ,Coll Phys & Optoelect Engn, Shenzhen 518060, Peoples R China
[2] Shenzhen Univ, Inst Translat Med, Shenzhen Peoples Hosp 2, Affiliated Hosp 1, Shenzhen 518035, Peoples R China
基金
中国国家自然科学基金;
关键词
2D materials; chemicals; energy; environment; single-atom catalysts; OXYGEN REDUCTION REACTION; N-C CATALYST; LIGHT PHOTOCATALYTIC DEGRADATION; GRAPHITIC CARBON NITRIDE; LAYERED DOUBLE HYDROXIDE; NITROGEN-DOPED GRAPHENE; WATER-GAS SHIFT; HYDROGEN EVOLUTION; SUPPORTED SINGLE; IN-SITU;
D O I
10.1002/advs.201901787
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recently, emerging 2D material-supported metal single-atom catalysts (SACs) are receiving enormous attention in heterogeneous catalysis. Due to their well-defined, precisely located metal centers, unique metal-support interaction and identical coordination environment, these catalysts serve as excellent models for understanding the fundamental issues in catalysis as well as exhibiting intriguing practical applications. Understanding the correlations between metal-support combinations and the catalytic performance at the atomic level can be achieved on the SACs@2D materials nanoplatforms. Herein, recent advances of metal SACs on various types of 2D materials are reviewed, especially their exciting applications in the fields of chemicals, energy, and the environment. Based on the summary and perspectives, this work should contribute to the rational design of perfect metal SACs with versatile properties.
引用
收藏
页数:35
相关论文
共 179 条
[1]   Tailoring the Edge Structure of Molybdenum Disulfide toward Electrocatalytic Reduction of Carbon Dioxide [J].
Abbasi, Pedram ;
Asadi, Mohammad ;
Liu, Cong ;
Sharifi-Asl, Soroosh ;
Sayahpour, Baharak ;
Behranginia, Amirhossein ;
Zapol, Peter ;
Shahbazian-Yassar, Reza ;
Curtiss, Larry A. ;
Salehi-Khojin, Amin .
ACS NANO, 2017, 11 (01) :453-460
[2]   Recent advances in emerging single atom confined two-dimensional materials for water splitting applications [J].
Alarawi, Abeer ;
Ramalingam, Vinoth ;
He, Jr-Hau .
MATERIALS TODAY ENERGY, 2019, 11 :1-23
[3]   High-Density Ultra-small Clusters and Single-Atom Fe Sites Embedded in Graphitic Carbon Nitride (g-C3N4) for Highly Efficient Catalytic Advanced Oxidation Processes [J].
An, Sufeng ;
Zhang, Guanghui ;
Wang, Tingwen ;
Zhan, Wenna ;
Li, Keyan ;
Song, Chunshan ;
Miller, Jeffrey T. ;
Miao, Shu ;
Wang, Junhu ;
Guo, Xinwen .
ACS NANO, 2018, 12 (09) :9441-9450
[4]  
[Anonymous], 2016, ANGEW CHEM
[5]   Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts [J].
Asokan, Chithra ;
DeRita, Leo ;
Christopher, Phillip .
CHINESE JOURNAL OF CATALYSIS, 2017, 38 (09) :1473-1480
[6]   Single Metal Atoms Anchored in Two-Dimensional Materials: Bifunctional Catalysts for Fuel Cell Applications [J].
Back, Seoin ;
Kulkarni, Ambarish R. ;
Siahrostami, Samira .
CHEMCATCHEM, 2018, 10 (14) :3034-3039
[7]   Superlattice of Single Atom Magnets on Graphene [J].
Baltic, Romana ;
Pivetta, Marina ;
Donati, Fabio ;
Wackerlin, Christian ;
Singha, Aparajita ;
Dreiser, Jan ;
Rusponi, Stefano ;
Brune, Harald .
NANO LETTERS, 2016, 16 (12) :7610-7615
[8]   Surface Immobilization of Transition Metal Ions on Nitrogen-Doped Graphene Realizing High-Efficient and Selective CO2 Reduction [J].
Bi, Wentuan ;
Li, Xiaogang ;
You, Rui ;
Chen, Minglong ;
Yuan, Ruilin ;
Huang, Weixin ;
Wu, Xiaojun ;
Chu, Wangsheng ;
Wu, Changzheng ;
Xie, Yi .
ADVANCED MATERIALS, 2018, 30 (18)
[9]   Single Pt Atom with Highly Vacant d-Orbital for Accelerating Photocatalytic H2 Evolution [J].
Cao, Yuanjie ;
Wang, Danhao ;
Lin, Yue ;
Liu, Wei ;
Cao, Linlin ;
Liu, Xiaokang ;
Zhang, Wei ;
Mou, Xiaoli ;
Fang, Shi ;
Shen, Xinyi ;
Yao, Tao .
ACS APPLIED ENERGY MATERIALS, 2018, 1 (11) :6082-6088
[10]   Atomic-Level Insight into Optimizing the Hydrogen Evolution Pathway over a Co1-N4 Single-Site Photocatalyst [J].
Cao, Yuanjie ;
Chen, Si ;
Luo, Qiquan ;
Yan, Huan ;
Lin, Yue ;
Liu, Wei ;
Cao, Linlin ;
Lu, Junling ;
Yang, Jinlong ;
Yao, Tao ;
Wei, Shiqiang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (40) :12191-12196