Mechanistic investigation of ZnO nanowire growth

被引:38
作者
Rackauskas, Simas [1 ,2 ]
Nasibulin, Albert G. [1 ,2 ]
Jiang, Hua [1 ,2 ]
Tian, Ying [1 ,2 ]
Statkute, Gintare [3 ]
Shandakov, Sergey D. [4 ]
Lipsanen, Harri [3 ]
Kauppinen, Esko I. [1 ,2 ,5 ]
机构
[1] Aalto Univ, Dept Appl Phys, Espoo 02015, Finland
[2] Aalto Univ, Ctr New Mat, NanoMat Grp, Espoo 02015, Finland
[3] Aalto Univ, Dept Micro & Nanosci, Espoo 02015, Finland
[4] Kemerovo State Univ, Dept Phys, Lab Carbon NanoMat, Kemerovo 650043, Russia
[5] VTT Biotechnol, Espoo 02044, Finland
基金
芬兰科学院;
关键词
diffusion; grain boundaries; II-VI semiconductors; interstitials; nanotechnology; nanowires; photoluminescence; vacancies (crystal); wide band gap semiconductors; zinc compounds; NANOSTRUCTURES; ARRAYS;
D O I
10.1063/1.3258074
中图分类号
O59 [应用物理学];
学科分类号
摘要
ZnO nanowire (NW) growth mechanism was investigated in a nonvapor and noncatalytic approach for the controlled NW synthesis in a second time scale. The experimental results showed what ZnO NW growth was determined by migration of zinc interstitials and vacancies in a ZnO layer, which should be also considered in other synthesis techniques and mechanisms. The mechanism of the ZnO NW growth was explained as due to the advantageous diffusion through grain boundaries in ZnO layer and crystal defects in NWs. Additionally, on the basis of photoluminescence measurements, a feasible application of as-produced wires for optoelectronic devices was demonstrated.
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页数:3
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