Carbon dioxide reduction with homogenous early transition metal complexes: Opportunities and challenges for developing CO2 catalysis

被引:167
作者
Grice, Kyle A. [1 ]
机构
[1] Depaul Univ, Dept Chem, 1110 West Belden Ave, Chicago, IL 60614 USA
关键词
CO2; reduction; Transition metals; Early metals; Catalysis; activation; GAS-DIFFUSION ELECTRODES; RAY CRYSTAL-STRUCTURE; ELECTROCHEMICAL REDUCTION; MOLECULAR-STRUCTURE; BONDING MODE; STRUCTURAL-CHARACTERIZATION; ELECTROCATALYTIC REDUCTION; PHOTOCATALYTIC REDUCTION; STOICHIOMETRIC REDUCTION; FORMALDEHYDE CHEMISTRY;
D O I
10.1016/j.ccr.2017.01.007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The field of carbon dioxide reduction by homogeneous early transition complexes (groups 3-7) is reviewed. Many reactions with CO2 have been studied with late transition metal complexes (groups 8-10), and significant progress has been made in developing active and selective homogeneous catalysts for CO2 reduction with late metals. However, one major drawback of these systems is that they generally only produce the 2e(-) reduction products CO or formate. In comparison, early transition metal complexes have been neglected for the development of CO2 reduction catalysts. Stoichiometric and catalytic reductions of CO2 to methanol and similar products have been observed with early transition metal complexes, and highly active catalysts may be developed based on early transition metal complexes that could reduce CO2 to liquid fuels such as methanol or to hydrocarbons such as methane. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:78 / 95
页数:18
相关论文
共 270 条
[1]   Design of a Catalytic Active Site for Electrochemical CO2 Reduction with Mn(I)-Tricarbonyl Species [J].
Agarwal, Jay ;
Shaw, Travis W. ;
Schaefer, Henry F., III ;
Bocarsly, Andrew B. .
INORGANIC CHEMISTRY, 2015, 54 (11) :5285-5294
[2]  
Agnew D.W., 2016, INORG CHEM
[3]  
Alonso FJG, 1996, J ORGANOMET CHEM, V511, P93
[4]   SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [MO(CO2)2(PME3)3(CNPRI)] - THE 1ST STRUCTURALLY CHARACTERIZED BIS(CARBON DIOXIDE) ADDUCT OF A TRANSITION-METAL [J].
ALVAREZ, R ;
CARMONA, E ;
GUTIERREZPUEBLA, E ;
MARIN, JM ;
MONGE, A ;
POVEDA, ML .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (20) :1326-1327
[5]   CARBON-DIOXIDE CHEMISTRY - SYNTHESIS, PROPERTIES, AND STRUCTURAL CHARACTERIZATION OF STABLE BIS(CARBON DIOXIDE) ADDUCTS OF MOLYBDENUM [J].
ALVAREZ, R ;
CARMONA, E ;
MARIN, JM ;
POVEDA, ML ;
GUTIERREZPUEBLA, E ;
MONGE, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2286-2294
[6]   CARBON-DIOXIDE CHEMISTRY - THE SYNTHESIS AND PROPERTIES OF TRANS-[MO(CO2)2(PME3)4] - THE 1ST STABLE BIS(CARBON DIOXIDE) ADDUCT OF A TRANSITION-METAL [J].
ALVAREZ, R ;
CARMONA, E ;
POVEDA, ML ;
SANCHEZDELGADO, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (09) :2731-2732
[7]   FORMATION OF ACRYLIC-ACID DERIVATIVES FROM THE REACTION OF CO2 WITH ETHYLENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN [J].
ALVAREZ, R ;
CARMONA, E ;
COLEHAMILTON, DJ ;
GALINDO, A ;
GUTIERREZPUEBLA, E ;
MONGE, A ;
POVEDA, ML ;
RUIZ, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (19) :5529-5531
[9]   Synthesis and characterization of new alkyl-carbon dioxide compounds and the first neutral acyl-carbonyl niobocene complexes [J].
Antinolo, A ;
CarrilloHermosilla, F ;
delHierro, I ;
Otero, A ;
Fajardo, M ;
Mugnier, Y .
ORGANOMETALLICS, 1997, 16 (19) :4161-4166
[10]   SYNTHESIS, ELECTROCHEMISTRY AND REACTIVITY OF FORMATO-NIOBOCENE AND ACETATO-NIOBOCENE COMPLEXES [J].
ANTINOLO, A ;
FAJARDO, M ;
GARCIAYUSTE, S ;
DELHIERRO, I ;
OTERO, A ;
ELKRAMI, S ;
MOURAD, Y ;
MUGNIER, Y .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (20) :3409-3414