The influence of the polymerization on properties of an ethylacrylate/2-ethyl hexylacrylate pressure-sensitive adhesive suspension

被引：32

作者：

Kajtna, J. ^{[2
]}

Likozar, B. ^{[1
]}

Golob, J. ^{[1
]}

Krajnc, M. ^{[1
]}

机构：

[1] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia

[2] Aero Dd, Celje 3000, Slovenia

来源：

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES | 2008年 / 28卷 / 07期

关键词：

pressure-sensitive; water based; infrared spectra; peel; microsphere;

D O I：

10.1016/j.ijadhadh.2007.11.003

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this paper, the batch suspension copolymerization process for production of microsphere acrylic pressure-sensitive adhesives (PSA) is presented. The effects of different process and chemical parameters on adhesion properties are discussed. The reaction was monitored in-line by using attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy. Properties of the adhesive suspension (particle size), adhesive (gel phase, molecular weight, glass transition temperature (T-g)) and adhesion properties (tack, peel strength and shear) were determined. The results have shown that reaction kinetics strongly depends on polymerization temperature and initiator concentration. On the other hand, adhesion properties depend mainly on the T-g of the polymer and on the amount of insoluble gel fraction in the adhesive. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：382 / 390

页数：9

共 29 条

[1] Continuous production of specialty waterborne adhesives: Tuning the adhesive performance [J].