Stability of Titanium-aluminium Nitride (Ti2AlN) at High Pressure and High Temperatures

被引：13

作者：

An Pei ^{[1
]}

He Zhilei ^{[2
]}

Qin Jiaqian ^{[1
]}

Li Ziyang ^{[1
]}

Li Yongjun ^{[1
]}

Kou Zili ^{[1
]}

He Duanwei ^{[1
]}

机构：

[1] Sichuan Univ, Inst Atom & Mol Phys, Chengdu 610065, Peoples R China

[2] Wuhan Univ Technol, Coll Mat Sci & Engn, Wuhan 430070, Peoples R China

来源：

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2011年 / 26卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Ti2AlN; high pressure and high temperature; stability; X-ray diffraction; PHASE THIN-FILMS; THERMAL-STABILITY; CRYSTAL-STRUCTURE; TI3SIC2; CARBIDE; TI3GEC2; TA4ALC3; COMPRESSION; TI3ALC2; GROWTH;

D O I：

10.1007/s11595-011-0336-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The stability of Ti2AlN at high pressure of 5 GPa and different temperatures of 700-1 600 degrees C was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDS). Ti2AlN was found to be stable at temperatures as high as 1 400 degrees C under 5 GPa for 20 min, and was proved that it held better structure stability than Ti2AlC under 5 GPa through comparative experiments of Ti2AlN and Ti2AlC (representative compounds of M(2)AX phases (211 phase)). The reaction process at high pressure had some difference from that at ambient pressure/vacuum, and Ti2AlN directly decomposed to TiN and TiAl at 5 GPa and 1 500 degrees C for 20 min. Moreover, the mechanism of phase segregation was discussed. In addition, the behavior of Ti2AlN contacting with Zr at high pressure and high temperature (HPHT) was also studied.

引用

页码：914 / 919

页数：6

共 43 条

[1] The topotactic transformation of Ti3SiC2 into a partially ordered cubic Ti(C0.67Si0.06) phase by the diffusion of Si into molten cryolite [J].

Barsoum, MW ;

El-Raghy, T ;

Farber, L ;

Amer, M ;

Christini, R ;

Adams, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (10) :3919-3923

[2] Processing and characterization of Ti2AlC, Ti2AlN, and Ti2AlC0.5N0.5 [J].

Barsoum, MW ;

Ali, M ;

El-Raghy, T .

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2000, 31 (07) :1857-1865

[3] The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates [J].

Barsoum, MW .

PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) :201-281

[4] Thermal stability of Ti3AlC2/Al2O3 composites in high vacuum [J].

Chen, J. X. ;

Zhou, Y. C. ;

Zhang, H. B. ;

Wan, D. T. ;

Liu, M. Y. .

MATERIALS CHEMISTRY AND PHYSICS, 2007, 104 (01) :109-112

[5] A new ternary nanolaminate carbide:: Ti3SnC2 [J].

Dubois, Sylvain ;

Cabioc'h, Thierry ;

Chartier, Patrick ;

Gauthier, Veronique ;

Jaouen, Michel .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (08) :2642-2644

[6] Ta4AlC3:: Phase determination, polymorphism and deformation [J].

Eklund, P. ;

Palmquist, J.-P. ;

Hoewing, J. ;

Trinh, D. H. ;

El-Raghy, T. ;

Hoegberg, H. ;

Hultman, L. .

ACTA MATERIALIA, 2007, 55 (14) :4723-4729

[7] Homoepitaxial growth of Ti-Si-C MAX-phase thin films on bulk Ti3SiC2 substrates [J].

Eklund, P. ;

Murugaiah, A. ;

Emmerlich, J. ;

Czigany, Zs. ;

Frodelius, J. ;

Barsoum, M. W. ;

Hogberg, H. ;

Hultman, L. .

JOURNAL OF CRYSTAL GROWTH, 2007, 304 (01) :264-269

[8] Thermal stability of Ti3SiC2 thin films [J].

Emmerlich, Jens ;

Music, Denis ;

Eklund, Per ;

Wilhelmsson, Ola ;

Jansson, Ulf ;

Schneider, Jochen M. ;

Hogberg, Hans ;

Hultman, Lars .

ACTA MATERIALIA, 2007, 55 (04) :1479-1488

[9] Ta3AlC2 and Ta4AlC3 -: Single-crystal investigations of two new ternary carbides of tantalum synthesized by the molten metal technique [J].

Etzkorn, Johannes ;

Ade, Martin ;

Hillebrecht, Harald .

INORGANIC CHEMISTRY, 2007, 46 (04) :1410-1418

[10] Effect of precompression on pressure-transmitting efficiency of pyrophyllite gaskets [J].

Fang, Leiming ;

He, Duanwei ;

Chen, Chao ;

Ding, Liye ;

Luo, Xiangjie .

HIGH PRESSURE RESEARCH, 2007, 27 (03) :367-374

← 1 2 3 4 5 →