Structure and Tensile Properties of Nanoclay-Polypropylene Fibers Produced by Melt Spinning

被引:20
作者
Rangasamy, Loganathan [1 ]
Shim, Eunkyoung [1 ]
Pourdeyhimi, Behnam [1 ]
机构
[1] N Carolina State Univ, Coll Text, Raleigh, NC 27695 USA
关键词
additives; extrusion; fibers; nanocomposites; poly(propylene) (PP); MECHANICAL-PROPERTIES; CRYSTALLIZATION BEHAVIORS; BLEND NANOCOMPOSITES; BARRIER PROPERTIES;
D O I
10.1002/app.33619
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanocomposite fibers of polypropylene and montmorillonite-based organoclay were produced by a melt-spinning process, and their structures and mechanical properties were studied. The addition of nanoclay in polypropylene increased the rate of crystallization and altered the microstructures of the fibers. Increases in the crystal size and a reduction in the molecular orientation were observed in the nanoclay-polypropylene composite fibers. The tensile properties of nanoclay composite fibers were also studied, and decreases in the fiber modulus and tenacity and increases in the strain at break were observed. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 410-419, 2011
引用
收藏
页码:410 / 419
页数:10
相关论文
共 35 条
[1]   Crystallization behavior and properties of exfoliated isotactic polypropylene/organoclay nanocomposites [J].
Avella, M ;
Cosco, S ;
Volpe, GD ;
Errico, ME .
ADVANCES IN POLYMER TECHNOLOGY, 2005, 24 (02) :132-144
[2]  
Avrami J., 1939, J CHEM PHYS, V7, P1103
[3]  
AVRAMI J, 1940, J CHEM PHYS, V8, P212
[4]   High barrier polyamide/polyolefin/organoday nanocomposites [J].
Brulé, B ;
Flat, JJ .
MACROMOLECULAR SYMPOSIA, 2006, 233 :210-216
[5]   Fracture properties of nanoclay-filled polypropylene [J].
Chen, L ;
Wong, SC ;
Pisharath, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (14) :3298-3305
[6]  
Cullity B. D., ELEMENTS XRAY DIFFRA
[7]   Clay exfoliation and organic modification on wear of nylon 6 nanocomposites processed by different routes [J].
Dasari, A ;
Yu, ZZ ;
Mai, YW ;
Hu, GH ;
Varlet, JL .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (15-16) :2314-2328
[8]   How organo-montmorillonite truly affects the structure and properties of polypropylene [J].
Ding, C ;
Jia, DM ;
He, H ;
Guo, BC ;
Hong, HQ .
POLYMER TESTING, 2005, 24 (01) :94-100
[9]  
Drodoz A.D., 2007, EUR POLYM J, V43, P10
[10]   Gas barrier properties of PP/EPDM blend nanocomposites [J].
Frounchi, Masoud ;
Dadbin, Susan ;
Salehpour, Zahra ;
Noferesti, Mohsen .
JOURNAL OF MEMBRANE SCIENCE, 2006, 282 (1-2) :142-148