Small CoFe2O4 magnetic nanoparticles in ferrofluids, influence of the synthesis on the magnetic anisotropies

被引:14
作者
Daffe, Nieli [1 ,2 ,3 ,4 ]
Gavrilov, Veronica [2 ]
Neveu, Sophie [2 ]
Choueikani, Fadi [3 ]
Arrio, Marie-Anne [1 ]
Juhin, Amelie [1 ]
Ohresser, Philippe [3 ]
Dupuis, Vincent [2 ]
Sainctavit, Philippe [1 ,3 ]
机构
[1] UPMC, UMR7590, CNRS, IMPMC,IRD,MNHN, F-75005 Paris, France
[2] Sorbonne Univ, CNRS, PHENIX, UMR8234, F-75005 Paris, France
[3] Synchrotron SOLEIL, LOrme Merisiers, St Aubin BP 48, F-91192 Gif Sur Yvette, France
[4] Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland
关键词
Anisotropies; XMCD; CoFe2O4; Spinel ferrite; Nanoparticles; X-RAY-ABSORPTION; COBALT FERRITE; GAMMA-FE2O3; NANOPARTICLES; CO; NANOCRYSTALS; HYDROLYSIS; DICHROISM; FE;
D O I
10.1016/j.jmmm.2019.01.048
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The magnetic properties of cobalt ferrites nanoparticles prepared using three different processes (thermal decomposition, polyol and co-precipitation synthesis routes) are investigated by X-ray Absorption Spectroscopy and X-ray Magnetic Circular Dichroism. The repartition of cobalt and iron ions amongst the interstitial sites of the spinel structure is determined and correlated with their magnetic properties. The study reports on the influence of the synthesis method on the crystallographic order within a nanoparticle, and hence, on the magnetic anisotropy.
引用
收藏
页码:226 / 231
页数:6
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