Facile Bucky-Bowl Synthesis by Regiospecific Cove-Region Closure by HF Elimination

被引：79

作者：

Amsharov, K. Yu ^{[1
]}

Kabdulov, M. A. ^{[1
]}

Jansen, Martin ^{[1
]}

机构：

[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 19期

关键词：

alumina; aryl-aryl coupling; buckybowls; C-F activation; HF elimination; SURFACE-CATALYZED CYCLODEHYDROGENATION; FLASH VACUUM PYROLYSIS; AROMATIC PRECURSORS; CHEMICAL-SYNTHESIS; HIGHER FULLERENES; END-CAP; POLYARENES; ARYLATION; CARBON; C-60;

D O I：

10.1002/anie.201200516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Building bowls: An effective intramolecular aryl-aryl coupling is the key step in rational fullerene synthesis and in synthesis of extended buckybowl structures. Such a process can be embodied very efficiently through quantitative HF elimination on active Al 2O 3. The process is characterized by an unprecedentedly high chemoselectivity and regiospecificity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4594 / 4597

页数：4

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