Structures and Inclusion Properties of Hydrogen-Bonded Host Frameworks Formed by 4,4′-(9-Fluorenylidene)diphenol and Diamines

被引：3
|
作者：
Clements, Monica [1 ]
le Roex, Tanya [1 ]
机构：
[1] Univ Stellenbosch, Dept Chem & Polymer Sci, Private Bag X1, ZA-7602 Matieland, South Africa
来源：
CRYSTAL GROWTH & DESIGN | 2016年 / 16卷 / 10期
基金：
新加坡国家研究基金会;
关键词：
ORGANIC FRAMEWORK; SURFACE-AREA; CRYSTAL; DESIGN; GUESTS;
D O I：
10.1021/acs.cgd.6b00937
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The combination of 4,4'-(9-fluorenylidene)diphenol with simple organic linkers resulted in the formation of a range of hydrogen-bonded frameworks with small guest molecules included in either cavities or channels within the structure. The structures of these host-guest compounds, as well as their properties, were investigated. It was found that the guest in one of these frameworks can be exchanged for a number of other solvents, and, in addition, selectivity experiments showed that this host framework preferentially includes acetone over tetrahydrofuran. Some of these structures can be formed mechanochemically by liquid-assisted grinding.
引用
收藏
页码：5869 / 5876
页数：8
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