Crystal-Plane-Controlled Surface Restructuring and Catalytic Performance of Oxide Nanocrystals

被引：149
作者：
Bao, Huizhi [1 ,2 ]
Zhang, Wenhua [3 ]
Hua, Qing [1 ,2 ]
Jiang, Zhiquan [1 ,2 ]
Yang, Jinlong [1 ,2 ]
Huang, Weixin [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Mat Energy Convers, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China
[3] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期
基金：
中国国家自然科学基金;
关键词：
Cu2O nanocrystals; nanocatalysis; oxidation; structure-activity relationships; surface chemistry; SHAPE CHANGES; CO OXIDATION; IN-SITU; RECONSTRUCTION; REACTIVITY; MECHANISM;
D O I：
10.1002/anie.201103698
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystal clear: Uniform Cu 2O nanooctahedra (o-Cu 2O) and nanocubes (c-Cu 2O) undergo surface restructuring during CO oxidation for the in-situ formation of catalytically active CuO thin films to give CuO/o-Cu 2O and CuO/c-Cu 2O, respectively (see picture). The structure and catalytic performance of CuO thin films are controlled by the crystal plane exposed on the underlying Cu 2O nanocrystals. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12294 / 12298
页数：5
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