Highly Effective Recyclable Palladium-Catalyzed Ligand-Free Heck Reactions under Aerobic Conditions

被引：10

作者：

Sun, Peng ^{[1
]}

Qu, Xiaoming ^{[1
]}

Li, Tingyi ^{[1
]}

Zhu, Yan ^{[1
]}

Yang, Hailong ^{[1
]}

Xing, Zeyong ^{[1
]}

Mao, Jincheng ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

SYNLETT | 2012年 / 23卷 / 01期

关键词：

coupling reactions; Heck reaction; aryl halides; olefins; ligand-free; IONIC LIQUIDS; NANOPARTICLES; EFFICIENT; ARYLATION; REGIOSELECTIVITY; CHEMISTRY; PHOSPHINE; OLEFINS;

D O I：

10.1055/s-0031-1290099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An effective protocol was developed for the Heck coupling reactions between various aryl halides and olefins. In the presence of 2 mol% of Pd(OAc)(2), the desired products could be obtained in good yields under ligand-free and aerobic conditions. The catalytic system could be easily recycled for five times with high efficiency.

引用

页码：150 / 154

页数：5

共 32 条

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