Self-healing thermoplastic elastomer brush copolymers having a glassy polymethylmethacrylate backbone and rubbery polyacrylate-amide brushes

被引:43
作者
Chen, Yulin [1 ]
Guan, Zhibin [1 ]
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
关键词
Self-healing materials; Brush copolymers; Thermoplastic elastomers; POLYMERIC MATERIALS;
D O I
10.1016/j.polymer.2015.03.023
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We synthesized a series of brush copolymers having glassy polymethylmethacrylate (PMMA) backbone and flexible polyacrylate-amide (PA-amide) brushes that exhibit thermoplastic elastomer properties. Importantly, the dynamic hydrogen bonds in the soft PA-amide matrix enables the material to self-heal after mechanical damage at room temperature without the need of any external stimulus. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:249 / 254
页数:6
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