Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids

被引：6

作者：

Li, Luan-Ying ^{[1
]}

Leng, Bo-Rong ^{[1
,2
]}

Li, Jia-Zhuo ^{[1
]}

Liu, Qing-Quan ^{[1
]}

Yu, Jianguang ^{[1
]}

Wei, Ping ^{[1
]}

Wang, De-Cai ^{[1
]}

Zhu, Yi-Long ^{[1
]}

机构：

[1] Nanjing Tech Univ, Sch Pharmaceut Sci, Nanjing 211816, Peoples R China

[2] Nanjing Polytech Inst, Coll Life & Hlth, Nanjing 210048, Peoples R China

来源：

RSC ADVANCES | 2022年 / 12卷 / 14期

关键词：

ALLYLIC SUBSTITUTION-REACTIONS; ASYMMETRIC-SYNTHESIS; SULFONYL HYDRAZIDES; HIGHLY REGIO; METAL; ALLENAMIDES; CHEMISTRY; ALDEHYDES; DIENES; AMINES;

D O I：

10.1039/d1ra09036d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E-allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.

引用

页码：8443 / 8448

页数：6

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