Structural diversity of silver (I) azine complexes - Effect of substituents and counter anions

被引：8

作者：

Patra, Goutam Kumar ^{[1
]}

Mukherjee, Anindita ^{[1
]}

Mitra, Partha ^{[2
]}

Adarsh, N. N. ^{[2
]}

机构：

[1] Vijoygarh Jyotish Ray Coll, Dept Chem, Kolkata 700032, India

[2] Indian Assoc Cultivat Sci, Dept Inorgan & Organ Chem, Kolkata 700032, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2011年 / 1000卷 / 1-3期

关键词：

Azine ligands; N-donor ligands; Silver (I) complex; Coordination polymer; Dimer; Crystal structure; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; HYBRID MATERIALS; ZIGZAG CHAINS; IMINE LIGANDS; COPPER(I); VARIABILITY; PYRIMIDINE; COBALT(II);

D O I：

10.1016/j.molstruc.2011.05.045

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three new Ag(I) complexes, 1, 2, and 3 of two azine ligands diacetyl dihydrazone (L1) and benzil dihydrazone (L2) have been synthesized and characterized by single crystal X-ray diffraction studies (for 2 and 3), X-ray powder diffraction studies(1 and 2), elemental analyses, IR and UV-VIS spectroscopy and TGA analysis. They represent one-dimensional polymeric assemblies and discrete dinuclear Ag(I) complex depending on functionality of the ligands and the counter anions. Tetrahedral as well as square pyramidal coordination motifs of the silver (I) ions have been observed in the supramolecular designing of such hybrid organic-inorganic materials. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：29 / 34

页数：6

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