Heteroatom-doped electrodes for all-vanadium redox flow batteries with ultralong lifespan

被引：93
作者：
Huang, Peng [1 ]
Ling, Wei [1 ]
Sheng, Hang [1 ]
Zhou, Yan [1 ]
Wu, Xiaopeng [3 ]
Zeng, Xian-Xiang [1 ]
Wu, Xiongwei [1 ]
Guo, Yu-Guo [2 ]
机构：
[1] Hunan Agr Univ, Coll Sci, Changsha 410128, Hunan, Peoples R China
[2] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
[3] Hunan Agr Univ, Agr Coll, Changsha 410128, Hunan, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2018年 / 6卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ELECTROCHEMICAL ENERGY-STORAGE; OXYGEN REDUCTION REACTION; LITHIUM ION BATTERIES; CARBON NANOTUBES; GRAPHITE FELT; POSITIVE ELECTRODE; OXIDE; CATALYST; CELL; PERFORMANCE;
D O I：
10.1039/c7ta07358e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The phosphorus and fluorine codoped graphite felt electrodes with prominent hydrophilicity present excellent electroactivity towards V2+/V3+ and VO2+/VO2+, elevate the discharging ability up to 250 mA cm(-2) and dramatically extend the energy efficiency of vanadium redox flow batteries towards 1000 cycles with 0.003% reduction per cycle.
引用
收藏
页码：41 / 44
页数：4
相关论文
共 48 条
[1]   Influence of fluorination on the properties of carbon fibres [J].
Bismarck, A ;
Tahhan, R ;
Springer, J ;
Schulz, A ;
Klapotke, TM ;
Zell, H .
JOURNAL OF FLUORINE CHEMISTRY, 1997, 84 (02) :127-134
[2]   Active sites engineering leads to exceptional ORR and OER bifunctionality in P,N Co-doped graphene frameworks [J].
Chai, Guo-Liang ;
Qiu, Kaipei ;
Qiao, Mo ;
Titirici, Maria-Magdalena ;
Shang, Congxiao ;
Guo, Zhengxiao .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (05) :1186-1195
[3]   A High-Performance Composite Electrode for Vanadium Redox Flow Batteries [J].
Deng, Qi ;
Huang, Peng ;
Zhou, Wen-Xin ;
Ma, Qiang ;
Zhou, Nan ;
Xie, Hao ;
Ling, Wei ;
Zhou, Chun-Jiao ;
Yin, Ya-Xia ;
Wu, Xiong-Wei ;
Lu, Xiang-Yang ;
Guo, Yu-Guo .
ADVANCED ENERGY MATERIALS, 2017, 7 (18)
[4]   Electrical Energy Storage for the Grid: A Battery of Choices [J].
Dunn, Bruce ;
Kamath, Haresh ;
Tarascon, Jean-Marie .
SCIENCE, 2011, 334 (6058) :928-935
[5]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[6]   Thermo-chemical treatments based on NH3/O2 for improved graphite-based fiber electrodes in vanadium redox flow batteries [J].
Flox, Cristina ;
Rubio-Garcia, Javier ;
Skoumal, Marcel ;
Andreu, Teresa ;
Ramon Morante, Juan .
CARBON, 2013, 60 :280-288
[7]   Thermally reduced graphite oxide as positive electrode in Vanadium Redox Flow Batteries [J].
Gonzalez, Zoraida ;
Botas, Cristina ;
Alvarez, Patricia ;
Roldan, Silvia ;
Blanco, Clara ;
Santamaria, Ricardo ;
Granda, Marcos ;
Menendez, Rosa .
CARBON, 2012, 50 (03) :828-834
[8]   Nanostructured materials for electrochemical energy conversion and storage devices [J].
Guo, Yu-Guo ;
Hu, Jin-Song ;
Wan, Li-Jun .
ADVANCED MATERIALS, 2008, 20 (15) :2878-2887
[9]   Graphene oxide nanosheets/multi-walled carbon nanotubes hybrid as an excellent electrocatalytic material towards VO2+/VO2+ redox couples for vanadium redox flow batteries [J].
Han, Pengxian ;
Yue, Yanhua ;
Liu, Zhihong ;
Xu, Wei ;
Zhang, Lixue ;
Xu, Hongxia ;
Dong, Shanmu ;
Cui, Guanglei .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) :4710-4717
[10]   Graphene oxide nanoplatelets as excellent electrochemical active materials for VO2+/VO2+ and V2+/V3+ redox couples for a vanadium redox flow battery [J].
Han, Pengxian ;
Wang, Haibo ;
Liu, Zhihong ;
Chen, Xiao ;
Ma, Wen ;
Yao, Jianhua ;
Zhu, Yuwei ;
Cui, Guanglei .
CARBON, 2011, 49 (02) :693-700
12345