Transformation of Metal-Organic Frameworks/Coordination Polymers into Functional Nanostructured Materials: Experimental Approaches Based on Mechanistic Insights

被引:188
作者
Lee, Kyung Joo [1 ]
Lee, Jae Hwa [1 ]
Jeoung, Sungeun [1 ]
Moone, Hoi Ri [1 ]
机构
[1] Ulsan Natl Inst Sci & Technol, Dept Chem, Sch Nat Sci, Ulsan 44919, South Korea
基金
新加坡国家研究基金会;
关键词
HIERARCHICALLY POROUS CARBON; HIGH-SURFACE-AREA; COORDINATION POLYMERS; FRAMEWORK; CONVERSION; STORAGE; ELECTROCATALYSTS; DECOMPOSITION; GRAPHENE; OXIDES;
D O I
10.1021/acs.accounts.7b00259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conspectus: Nanostructured materials such as porous metal oxides, metal nanoparticles, porous carbons, and their composites have been intensively studied due to their applications, including energy conversion and storage devices, catalysis, and gas storage. Appropriate precursors and synthetic methods are chosen for synthesizing the target materials. About a decade ago, metalorganic frameworks (MOFs) and coordination polymers (CPs) emerged as new precursors for these nanomaterials because they contain both organic and inorganic species that can play parallel roles as both a template and a precursor under given circumstances. Thermal conversions of MOFs offer a promising toolbox for synthesizing functional nanomaterials that are difficult to obtain using conventional methods. Although understanding the conversion mechanism is important for designing MOF precursors for the synthesis of nanomaterials with desired physicochemical properties, comprehensive discussions revealing the transformation mechanism remain insufficient. This Account reviews the utilization of MOFs/CPs as precursors and their transformation into functional nanomaterials with a special emphasis on understanding the relationship between the intrinsic nature of the parent MOFs and the daughter nanomaterials while discussing various experimental approaches based on mechanistic insights. We discuss nanomaterials categorized by materials such as metal-based nanomaterials and porous carbons. For metal-based nanomaterials transformed from MOFs, the nature of metal ions in the MOF scaffolds affects the physicochemical properties of the resultant materials including the phase, composite, and morphology of nanomaterials. Organic ligands are also involved in the in situ chemical reactions with metal species during thermal conversion. We describe these conversion mechanisms by classifying the phase of metal components in the resultant materials. Along with the metal species, carbon is a major element in MOFs, and thus, the appropriate choice of precursor MOFs and heat treatment can be expected to yield carbon-based nanomaterials. We address the relationship between the nature of the parent MOF and the porosity of the daughter carbon materiala controversial issue in the synthesis of porous carbons. Based on an understanding of the mechanism of MOF conversion, morphologically or compositionally advanced materials are synthesized by adopting appropriate MOF precursors and thermolysis conditions. Despite the progressive understanding of conversion phenomena of MOFs/CPs, this research field still has rooms to be explored and developed, ultimately in order to precisely control the properties of resultant nanomaterials. In this sense, we should pay more attention to the mechanism investigations of MOF conversion. We believe this Account will facilitate a deeper understanding of MOF/CP conversion routes and will accelerate further development in this field.
引用
收藏
页码:2684 / 2692
页数:9
相关论文
共 44 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Coordination polymers, metal-organic frameworks and the need for terminology guidelines [J].
Batten, Stuart R. ;
Champness, Neil R. ;
Chen, Xiao-Ming ;
Garcia-Martinez, Javier ;
Kitagawa, Susumu ;
Ohrstrom, Lars ;
O'Keeffe, Michael ;
Suh, Myunghyun Paik ;
Reedijk, Jan .
CRYSTENGCOMM, 2012, 14 (09) :3001-3004
[3]   Metal Organic Framework-Derived Metal Phosphates as Electrode Materials for Supercapacitors [J].
Bendi, Ramaraju ;
Kumar, Vipin ;
Bhavanasi, Venkateswarlu ;
Parida, Kaushik ;
Lee, Pooi See .
ADVANCED ENERGY MATERIALS, 2016, 6 (03)
[4]   Stepwise Synthesis of Metal-Organic Frameworks [J].
Bosch, Mathieu ;
Yuan, Shuai ;
Rutledge, William ;
Zhou, Hong-Cai .
ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (04) :857-865
[5]   Metal and metal oxide nanoparticle synthesis from metal organic frameworks (MOFs): finding the border of metal and metal oxides [J].
Das, Raja ;
Pachfule, Pradip ;
Banerjee, Rahul ;
Poddar, Pankaj .
NANOSCALE, 2012, 4 (02) :591-599
[6]   Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction [J].
Deng, Jiao ;
Ren, Pengju ;
Deng, Dehui ;
Bao, Xinhe .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (07) :2100-2104
[7]   Structure, Bonding, and Catalytic Activity of Monodisperse, Transition-Metal-Substituted CeO2 Nanoparticles [J].
Elias, Joseph S. ;
Risch, Marcel ;
Giordano, Livia ;
Mansour, Azzam N. ;
Shao-Horn, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (49) :17193-17200
[8]   Phosphorous-Nitrogen-Codoped Carbon Materials Derived from Metal-Organic Frameworks as Efficient Electrocatalysts for Oxygen Reduction Reactions [J].
Fu, Yu'ang ;
Huang, Yan ;
Xiang, Zhonghua ;
Liu, Guangqing ;
Cao, Dapeng .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (13-14) :2100-2105
[9]   Formation of Onion-Like NiCo2S4 Particles via Sequential Ion-Exchange for Hybrid Supercapacitors [J].
Guan, Bu Yuan ;
Yu, Le ;
Wang, Xiao ;
Song, Shuyan ;
Lou, Xiong Wen .
ADVANCED MATERIALS, 2017, 29 (06)
[10]   In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors [J].
Jeon, Ju-Won ;
Sharma, Ronish ;
Meduri, Praveen ;
Arey, Bruce W. ;
Schaef, Herbert T. ;
Lutkenhaus, Jodie L. ;
Lemmon, John P. ;
Thallapally, Praveen K. ;
Nandasiri, Manjula I. ;
McGrail, Benard Peter ;
Nune, Satish K. .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) :7214-7222