Highly Efficient Amide Synthesis from Alcohols and Amines by Virtue of a Water-Soluble Gold/DNA Catalyst

被引：225
|
作者：
Wang, Ye [1 ,2 ]
Zhu, Dapeng [1 ,2 ]
Tang, Lin [1 ,2 ]
Wang, Sujing [1 ,2 ]
Wang, Zhiyong [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 38期
关键词：
amidation; DNA; gold; heterogeneous catalysis; oxidation; AEROBIC OXIDATION; ARYL HALIDES; SELECTIVE OXIDATION; ORGANIC-SYNTHESIS; BOND FORMATION; N-FORMYLATION; ALDEHYDES; NANOPARTICLES; AMINOCARBONYLATION; REACTIVITY;
D O I：
10.1002/anie.201102374
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold takes to water: The synthesis of amides directly from alcohols and amines was realized by using a water-soluble Au/DNA nanohybrid as the catalyst. The interactions between the gold nanoparticles, DNA, and water lead to high catalytic efficiency under mild reaction conditions. The wide substrate scope includes less-basic aromatic amines, and this catalyst is recyclable. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8917 / 8921
页数：5
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