Asymmetric synthesis of aziridine 2-phosphonates and azirinyl phosphonates from enantiopure sulfinimines

被引：72
作者：
Davis, FA [1 ]
McCoull, W [1 ]
机构：
[1] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 02期
关键词：
D O I：
10.1016/S0040-4039(98)02331-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Enantiopure sulfinimine (S)-4 was employed in a Darzens-type synthesis of aziridine 2-phosphonates (-)-7/(+)-8 which were transformed into alpha-amino phosphonates (S)-11/(R)-12 and the first enantiopure examples of azirinyl phosphonates 13-15. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码：249 / 252
页数：4
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