Phenanthroline-appended porphyrazines: synthesis and conversion into solitaire Ru(II) complexes

被引：22

作者：

Montalban, AG

Sakellariou, EG

Riguet, E

McCubbin, QJ

Barrett, AGM ^{[1
]}

Hoffman, BM

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

INORGANICA CHIMICA ACTA | 2001年 / 317卷 / 1-2期

基金：

英国工程与自然科学研究理事会; 美国国家科学基金会;

关键词：

porphyrinoid complexes; phenanthroline complexes; ruthenium complexes;

D O I：

10.1016/S0020-1693(01)00325-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Unsymmetrical porphyrazines (tetraazaporphyrins) bearing a single bidentate phenanthroline chelating group M[pz(t-butylphenyl)(6)phen] have been prepared by the base-catalyzed cross condensation of 3,4-bis(4-tert-butylphenyl)pyrroline-2,5-diimine (in excess) with 6,7-dicyanodipyridoquinoxaline. Treatment of these centrally metalated (M = Mg, Zn) ligands with various Ru(II) salts has yielded several bimetallic complexes including the first coordinatively linked porphyrazine trimer. The optical properties of these complexes are shown to be a function of the additional ligands surrounding the asymmetric ruthenium center. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：143 / 148

页数：6

共 19 条

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