Recycled Pd/C-Catalyzed Heck Reaction of 2-Iodoanilines under Ligand-Free Conditions

被引：7

作者：

Zhou, Xiao-Yu ^{[1
]}

Chen, Xia ^{[1
]}

Wang, Liang-Guang ^{[2
]}

机构：

[1] Liupanshui Normal Univ, Coll Chem & Mat Engn, Liupanshui 553004, Peoples R China

[2] Anshun Univ, Coll Chem & Chem Engn, Anshun 561000, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2017年 / 49卷 / 24期

关键词：

palladium; heterogeneous catalysis; Heck reaction; ligand-free; 2-iodoaniline; CROSS-COUPLING REACTIONS; ARYL CHLORIDES; IONIC LIQUIDS; C-C; ORGANIC-SYNTHESIS; MILD CONDITIONS; PALLADIUM; BROMIDES; TEMPERATURE; CYCLIZATION;

D O I：

10.1055/s-0036-1590895

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recyclable Pd/C-catalyzed Heck reaction of 2-iodoanilines with acrylate has been developed. The reaction occurred readily in 1,4-dioxane using Pd/C (10 wt%) as catalyst under ligand-free conditions, and the cross-coupling products were obtained with medium to high yield. Gram-scale reactions and recycling of the catalyst were also demonstrated.

引用

页码：5364 / 5370

页数：7