Spectroscopic properties of vacancies and trap levels in Lu3Al5O12:Ce3+ crystals

被引:11
作者
Zhong Jiu-ping [1 ]
Liang Hong-bin [1 ]
Su Qiang [1 ]
Zhou Jian-ying [1 ]
Wang Ji-yang [2 ]
机构
[1] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
基金
中国博士后科学基金;
关键词
Lu3Al5O12:Ce3+ crystal; oxygen vacancy; thermoluminescence; DEFECTS CREATION; ELECTRON TRAPS; SCINTILLATORS; LUMINESCENCE; PEROVSKITES; YALO3-CE; LUALO3-CE; ALUMINUM; GARNETS;
D O I
10.1016/S1003-6326(09)60080-7
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
In order to study the spectroscopic properties of vacancies and trap levels in Lu3Al5O12:Ce3+ (LuAG:Ce3+) crystal, the < 111 >-oriented LuAG:Ce3+ crystal grown in pure nitrogen atmosphere by Czochralski method was annealed in oxidizing atmosphere (air) and reducing atmosphere (H-2+N-2), respectively. The excitation and emission spectra of LuAG:Ce3+ crystal after different thermal annealing treatments were measured in the temperature range of 8-450 K, and the thermally stimulated luminescence curves of LuAG:Ce3+ crystal were characterized. It is found that the oxygen vacancies in LuAG:Ce3+ crystal are effectively eliminated through the annealing treatment in air and four trap levels are observed in as-grown LuAG:Ce3+ crystal with temperature position peaking at 110, 210, 325 and 475 degrees C, respectively.
引用
收藏
页码:1628 / 1633
页数:6
相关论文
共 14 条
[1]   Electron traps and transfer efficiency of cerium-doped aluminate scintillators [J].
Bartram, RH ;
Hamilton, DS ;
Kappers, LA ;
Lempicki, A .
JOURNAL OF LUMINESCENCE, 1997, 75 (03) :183-192
[2]   Luminescence and defects creation in Ce3+-doped Lu3Al5O12 crystals [J].
Blazek, K ;
Krasnikov, A ;
Nejezchleb, K ;
Nikl, M ;
Savikhina, T ;
Zazubovich, S .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2004, 241 (05) :1134-1140
[3]   Shallow traps in YAlO3: Ce single crystal perovskites [J].
Fasoli, Mauro ;
Fontana, Ilaria ;
Moretti, Federico ;
Vedda, Anna ;
Nikl, Martin ;
Mihokova, Eva ;
Zorenko, Yuriy V. ;
Gorbenko, Vitalyi I. .
IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2008, 55 (03) :1114-1117
[4]   Luminescence and defects creation in Ce3+-doped aluminium and lutetium perovskites and garnets [J].
Krasnikov, A ;
Savikhina, T ;
Zazubovich, S ;
Nikl, M ;
Mares, JA ;
Blazek, K ;
Nejezchleb, K .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2005, 537 (1-2) :130-133
[5]   Ce3+-doped scintillators:: status and properties of (Y,Lu) aluminium perovskites and garnets [J].
Mares, JA ;
Nikl, M ;
Beitlerova, A ;
Solovieva, N ;
D'Ambrosio, C ;
Blazek, K ;
Maly, P ;
Nejezchleb, K ;
Fabeni, P ;
Pazzi, GP .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2005, 537 (1-2) :271-275
[6]  
MEIJVOGEL K, 1996, P INT C IN SCINT THE, P159
[7]  
Nikl M, 2000, PHYS STATUS SOLIDI A, V181, pR10, DOI 10.1002/1521-396X(200009)181:1<R10::AID-PSSA999910>3.0.CO
[8]  
2-9
[9]   Inorganic scintillators: today and tomorrow [J].
Weber, MJ .
JOURNAL OF LUMINESCENCE, 2002, 100 (1-4) :35-45
[10]   Electron traps and scintillation mechanism in YAlO3:Ce and LuAlO3:Ce scintillators [J].
Wojtowicz, AJ ;
Glodo, J ;
Drozdowski, W ;
Przegietka, KR .
JOURNAL OF LUMINESCENCE, 1998, 79 (04) :275-291