Photoluminescence of orthorhombic Li2Mg2(MoO4)3 crystal doped with Yb3+ ions

被引:0
作者
Bhave, M. M. [1 ]
Tupte, B., V [2 ]
Mungmode, C. D. [3 ]
Gahane, D. H. [4 ]
Moharil, S., V [5 ]
机构
[1] NH Coll, Dept Phys, Bramhapuri 441206, MS, India
[2] SGM Coll, Dept Phys, Kurkheda 441209, MS, India
[3] MG Coll, Dept Phys, Armori 441208, MS, India
[4] NH Coll, Dept Elect, Bramhapuri 441206, MS, India
[5] RTM Nagpur Univ, Dept Phys, Nagpur 440010, MS, India
来源
INTERNATIONAL CONFERENCE ON MULTIDIMENSIONAL ROLE OF BASIC SCIENCE IN ADVANCED TECHNOLOGY (ICMBAT 2018) | 2019年 / 2104卷
关键词
Phosphors; Combustion Method; Li2Mg2(MoO4)(3) crystal; Luminescence; tunable laser; TUNABLE LASER OPERATION; SPECTROSCOPIC CHARACTERISTICS; GROWTH; LUMINESCENCE; MOLYBDATE;
D O I
10.1063/1.5100465
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The lithium magnesium molybdate Li2-2xMg2+x (MoO4)(3): xYb(3+) (x= 0.01, 0.03, 0.05 and 0.07) phosphors were prepared by combustion synthesis method at 750 degrees C. The phases of prepared phosphors were confirmed by X-ray diffraction pattern and luminescent properties of phosphor materials were systematically studied. Li2Mg2(MoO4)(3) has an orthorhombic symmetry and has discovered a three-dimensional framework consisting of metal-oxygen octahedra and trigonal prisms (where Li and Mg reside) that are interconnected by Moth tetrahedra. As a result of host absorption of Li2Mg2(MoO4)(3), a broad excitation band ranging from 200 to 400 nm is recorded when Yb3+ emission was observed, photoluminescence spectra measured suggests the efficient energy transfer from host to Yb3+ ions. Upon ultraviolet excitation, an intense near-infrared emission of Yb3+ (F-2(5/2) -> F-2(7/2)) around 986 nm is observed in Li2Mg2(MoO4)(3): Yb3+. All the results indicate that Yb3+ doped Li2Mg2(MoO4)(3) crystal can serve as UV excited phosphor that is a promising candidate as an associated application for the tunable laser.
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页数:5
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