Synthesis of furoxan derivatives based on 4-aminofuroxan-3-carboxylic acid azide

被引:47
作者
Kulikov, AS [1 ]
Ovchinnikov, IV [1 ]
Molotov, SI [1 ]
Makhova, NN [1 ]
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
关键词
furoxans; azides; hydroxamic acids; azo and azoxy derivatives; oxidation; nucleophilic substitution; dehydration; nitriles;
D O I
10.1023/A:1026073108494
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A convenient preparative method was developed for the synthesis of 4-amino-3-furoxancarboxylic acid azide, which is a universal synthon for the preparation of functional furoxan derivatives. This method was used for preparing new azo-, azoxy-, azido-, cyano-, nitro-, carbonylamino-, and hydroxylamino-substituted furoxan derivatives, which have earlier been difficultly accessible.
引用
收藏
页码:1822 / 1828
页数:7
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