μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate

被引:1
作者
Golobic, Amalija [1 ]
Ceh, Boris [1 ]
机构
[1] Univ Ljubljana, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
HETEROSCORPIONATE LIGANDS; COMPLEXES; CHEMISTRY;
D O I
10.1107/S1600536810045393
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the binuclear title compound, [Mo-2(C12H15N4O2)(2)Cl2O3]center dot-H2O, the complex molecules have approximate C-2 symmetry. Both Mo-V atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo-V atom via an N2O donor set. The water molecule bridges two complex molecules, forming O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds to the acetate group and to the chloride ligands.
引用
收藏
页码:M1648 / U1484
页数:12
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