Trace gas adsorption thermodynamics at the air-water interface: Implications in atmospheric chemistry

被引：25
|
作者：
Valsaraj, Kalliat T. [1 ]
机构：
[1] Louisiana State Univ, Cain Dept Chem Engn, Baton Rouge, LA 70803 USA
来源：
PURE AND APPLIED CHEMISTRY | 2009年 / 81卷 / 10期
基金：
美国国家科学基金会;
关键词：
atmospheric oxidation; gas adsorption; polycyclic aromatic hydrocarbons; thermodynamics; water thin films; POLYCYCLIC AROMATIC-HYDROCARBONS; VOLATILE ORGANIC-COMPOUNDS; AQUEOUS SURFACES; AIR/WATER INTERFACE; MOLECULAR-DYNAMICS; OZONE DEPLETION; REACTIVE UPTAKE; VAPORS; SOLVATION; AEROSOLS;
D O I：
10.1351/PAC-CON-08-07-06
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The thermodynamics of adsorption of gaseous organic compounds such as polycyclic aromatic hydrocarbons (PAHs) on water films is reviewed and discussed. The various experimental methods available to determine the thermodynamic equilibrium constant and the structure-activity relationships to correlate and estimate the same are reviewed. The atmospheric implications of the adsorption and oxidation of PAHs at the air-water interface of thin films of water such as existing in fog droplets, ice films, and aerosols are also enumerated.
引用
收藏
页码：1889 / 1901
页数：13
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