Polyoxometalate-based {Mn2III}-Schiff base composite materials exhibiting single-molecule magnet behaviour

被引：65
|
作者：
Wu, Qiong [1 ]
Li, Yang-Guang [1 ]
Wang, Yong-Hui [1 ]
Clerac, Rodolphe [2 ,3 ]
Lu, Ying [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
[2] CNRS, Ctr Rech Paul Pascal, UPR 8641, Equipe Mat Mol Magnet, F-33600 Pessac, France
[3] Univ Bordeaux, UPR 8641, F-33600 Pessac, France
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 38期
基金：
中国国家自然科学基金;
关键词：
BUILDING-BLOCKS; SLOW RELAXATION; MAGNETIZATION; COMPLEXES; SALEN; EXCHANGE; STATE; DIMER;
D O I：
10.1039/b909246c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The introduction of [Mn(salen)(H2O)](2)(ClO4)(2)center dot H2O ({Mn-2(III)}) into the polyoxometalate (POM) systems Na-3[XMo6(OH)(6)O-18] (X = Al and Cr) led to the isolation of new {Mn-2(III)}-POM composite materials with single-molecule magnetic behaviour.
引用
收藏
页码：5743 / 5745
页数：3
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