Fabrication of Pt/CeO2 nanofibers for use in water-gas shift reaction

被引：24

作者：

Tang, Huijuan ^{[1
]}

Sun, Haiyan ^{[1
]}

Chen, Dairong ^{[1
]}

Jiao, Xiuling ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Educ Minist, Key Lab Special Funct Aggregate Mat, Jinan 250100, Peoples R China

来源：

MATERIALS LETTERS | 2012年 / 77卷

关键词：

Pt/CeO2; Sol-gel preparation; Electrospinning; Fiber technology; Water-gas shift reaction; NOBLE-METAL CATALYSTS; PD;

D O I：

10.1016/j.matlet.2012.02.122

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The Pt/CeO2 nanofibers with diameter of 80-120 nm were prepared by electrospinning method with Ce(NO3)(3)center dot 6H(2)O as raw material and PVP as spinnable additive. This method included the preparation of spinnable sol and electrospinning process. After calcination at 400 degrees C, the fluorite structure Pt/CeO2 nanofibers with loose structure were obtained, which were composed of 5-10 nm particles. In the water-gas shift reaction, 1 wt.% Pt doped CeO2 nanofibers exhibited superior catalytic activity compared with pure CeO2 nanofiber, Pt loaded CeO2 powder and Pt loaded CeO2 nanofiber, and the CO conversion reaches 98% at 320 degrees C and maintains that until 360 degrees C, showing potential application in water-gas shift reaction. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：7 / 9

页数：3

共 17 条

[1] Low-temperature water-gas shift reaction over Au/CeO2 catalysts [J].