Trinuclear rhodium hydride complexes

被引：19
作者：
Fischer, Christian [1 ]
Kohrt, Christina [1 ]
Drexler, Hans-Joachim [1 ]
Baumann, Wolfgang [1 ]
Heller, Detlef [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 16期
关键词：
CATALYZED ASYMMETRIC HYDROGENATION; PARAHYDROGEN-INDUCED POLARIZATION; HOMOGENEOUS HYDROGENATION; METAL-CLUSTERS; ENANTIOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; MOLECULAR-STRUCTURE; CATIONIC COMPLEXES; X-RAY; OLEFINS;
D O I：
10.1039/c0dt01564d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H]3(μ2-H)3(μ3- H)}[BF4]2 containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution. © 2011 The Royal Society of Chemistry.
引用
收藏
页码：4162 / 4166
页数：5
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