Trinuclear rhodium hydride complexes

被引：19

作者：

Fischer, Christian ^{[1
]}

Kohrt, Christina ^{[1
]}

Drexler, Hans-Joachim ^{[1
]}

Baumann, Wolfgang ^{[1
]}

Heller, Detlef ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 16期

关键词：

CATALYZED ASYMMETRIC HYDROGENATION; PARAHYDROGEN-INDUCED POLARIZATION; HOMOGENEOUS HYDROGENATION; METAL-CLUSTERS; ENANTIOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; MOLECULAR-STRUCTURE; CATIONIC COMPLEXES; X-RAY; OLEFINS;

D O I：

10.1039/c0dt01564d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H]3(μ2-H)3(μ3- H)}[BF4]2 containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution. © 2011 The Royal Society of Chemistry.

引用

页码：4162 / 4166

页数：5

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