A new P-chiral bisphosphine, 1,1′-bis[(t-butyl)methylphosphino]ferrocene, as an effective ligand in catalytic asymmetric hydrosilylation of simple ketones

被引：55

作者：

Tsuruta, H ^{[1
]}

Imamoto, T ^{[1
]}

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(99)00042-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric hydrosilylation of simple ketones was catalyzed by a rhodium complex with a P-chiral bisphosphine, 1,1'-bis[(t-butyl)methylphosphino] ferrocene, to give optically active alcohols with enantiomeric excesses of up to 92%. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：877 / 882

页数：6

共 10 条

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[2] A NEW P-CHIRAL BISPHOSPHINE, (S,S)-1,2-BIS(O-ETHYLPHENYL)PHENYL-PHOSPHINOETHANE, AS AN EFFECTIVE LIGAND IN CATALYTIC ASYMMETRIC HYDROGENATION OF ALPHA-(ACYLAMINO)ACRYLIC ACIDS
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TETRAHEDRON LETTERS, 1995, 36 (45) : 8271 - 8274
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Chang, Shirui
Wang, Lei
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ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (13) : 2239 - 2247
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Fukuzawa, S
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Matsuzawa, H
ORGANIC LETTERS, 2002, 4 (05) : 707 - 709
[6] OPTICALLY-ACTIVE 2,2'-BIS(DIPHENYLPHOSPHINOMETHYL)-1,1'-BINAPHTHYL - NEW CHIRAL BIDENTATE PHOSPHINE LIGAND FOR TRANSITION-METAL COMPLEX CATALYZED ASYMMETRIC REACTIONS
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TETRAHEDRON LETTERS, 1977, (16) : 1389 - 1392
[7] Design and preparation of 3,3′-disubstituted 2,2′-bis(oxazolyl)-1,1′-binaphthyls (boxax):: New chiral bis(oxazoline) ligands for catalytic asymmetric Wacker-type cyclization
Uozumi, Y
Kyota, H
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JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (05): : 1620 - 1625
[8] Catalytic Asymmetric Oxidation of Heteroaromatic Sulfides with tert-Butyl Hydroperoxide Catalyzed by a Titanium Complex with a New Chiral 1,2-Diphenylethane-1,2-diol Ligand
Jiang, Biao
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EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (07) : 987 - 991
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J Org Chem, 2-5 (1620-1625):
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