Ambipolar organic field effect transistors and inverters with the natural material Tyrian Purple

被引:66
作者
Glowacki, Eric Daniel [1 ]
Leonat, Lucia [2 ,3 ]
Voss, Gundula [5 ]
Bodea, Marius-Aurel [4 ]
Bozkurt, Zeynep [6 ]
Ramil, Alberto Montaigne [1 ]
Irimia-Vladu, Mihai [1 ]
Bauer, Siegfried
Sariciftci, Niyazi Serdar [1 ]
机构
[1] Johannes Kepler Univ Linz, Linz Inst Organ Solar Cells LIOS, A-4040 Linz, Austria
[2] Natl Inst Elect Engn, IPCE CA, Bucharest, Romania
[3] Univ Politehn Bucuresti, Fac Appl Chem & Mat Sci, Bucharest, Romania
[4] Johannes Kepler Univ Linz, Inst Appl Phys, A-4040 Linz, Austria
[5] Univ Bayreuth, Dept Bioorgan Chem, D-95440 Bayreuth, Germany
[6] Sabanci Univ, Dept Mat Sci & Engn, Istanbul, Turkey
关键词
D O I
10.1063/1.3660358
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ambipolar organic semiconductors enable complementary-like circuits in organic electronics. Here we show promising electron and hole transport properties in the natural pigment Tyrian Purple (6,6'-dibromoindigo). X-ray diffraction of Tyrian Purple films reveals a highly-ordered structure with a single preferential orientation, attributed to intermolecular hydrogen bonding. This material, with a band gap of similar to 1.8 eV, demonstrates high hole and electron mobilities of 0.22 cm(2)/V u s and 0.03 cm(2)/V . s in transistors, respectively; and air-stable operation. Inverters with gains of 250 in the first and third quadrant show the large potential of Tyrian Purple for the development of integrated organic electronic circuits. Copyright 2011 Author(s). This article is distributed under a Creative Commons Attribution 3.0 Unported License. [doi: 10.1063/1.3660358]
引用
收藏
页数:6
相关论文
共 29 条
[1]  
[Anonymous], 1954, HEBD SEANCES ACAD SC, V239, P975
[2]  
[Anonymous], 1987, Organic Chemistry in Colour
[3]  
[Anonymous], 2010, AFR J PURE APPL CHEM, DOI DOI 10.5897/AJPAC.9000034
[4]   Air-stable ambipolar organic transistors [J].
Anthopoulos, Thomas D. ;
Anyfantis, G. C. ;
Papavassiliou, G. C. ;
de Leeuw, Dago M. .
APPLIED PHYSICS LETTERS, 2007, 90 (12)
[5]   Air-stable complementary-like circuits based on organic ambipolar transistors [J].
Anthopoulos, Thomas D. ;
Setayesh, Sepas ;
Smits, Edsger ;
Colle, Michael ;
Cantatore, Eugenio ;
de Boer, Bert ;
Blom, Paul W. M. ;
de Leeuw, Dago M. .
ADVANCED MATERIALS, 2006, 18 (14) :1900-+
[6]  
Baker R.Jacob., 2007, IEEE Press Series on Microelectronic Systems
[7]   High Mobility Ambipolar Charge Transport in Polyselenophene Conjugated Polymers [J].
Chen, Zhuoying ;
Lemke, Henrik ;
Albert-Seifried, Sebastian ;
Caironi, Mario ;
Nielsen, Martin Meedom ;
Heeney, Martin ;
Zhang, Weimin ;
McCulloch, Iain ;
Sirringhaus, Henning .
ADVANCED MATERIALS, 2010, 22 (21) :2371-2375
[8]   Poly(diketopyrrolopyrrole-benzothiadiazole) with Ambipolarity Approaching 100% Equivalency [J].
Cho, Shinuk ;
Lee, Junghoon ;
Tong, Minghong ;
Seo, Jung Hwa ;
Yang, Changduk .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (10) :1910-1916
[9]  
Cooksey C.J., 1994, DYES HIST ARCHAEOLOG, V13, P7
[10]   Tyrian purple:: 6,6′-dibromoindigo and related compounds [J].
Cooksey, CJ .
MOLECULES, 2001, 6 (09) :736-769