Pd-Catalyzed One-Pot Insertion Reaction of Cyclic C-Acylimines into Carbon-Carbon σ-Bonds for the Synthesis of Polyfunctional Indolin-3-ones from 2-Alkynyl Arylazides and Aryl Ketones

被引：26

作者：

Li, Ping ^{[1
]}

Yong, Wanxiong ^{[1
]}

Sheng, Rong ^{[1
]}

Rao, Weidong ^{[1
]}

Zhu, Xinbao ^{[1
]}

Zhang, Xiaoxiang ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Jiangsu, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Pd-catalyzed; insertion reaction; cyclic C-acylimines; polyfunctionalindolin-3-ones; ENANTIOSELECTIVE SYNTHESIS; N-TOSYLHYDRAZONES; FACILE INSERTION; REDOX ANNULATION; RAPID ACCESS; IN-SITU; ARYNES; INDOLES; DERIVATIVES; MIGRATION;

D O I：

10.1002/adsc.201801162

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A method to prepare polyfunctional indolin-3-ones by Pd-catalyzed one-pot insertion reaction of cyclic C-acylimines into carbon-carbon sigma-bonds is described. The reaction was accomplished in good to excellent yields under mild reaction conditions.

引用

页码：201 / 207

页数：7

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