PbTiO3-Ni0.5Co0.5Fe2O4 multiferroic nanocomposites: Impact of ball-milling on dielectric, magnetic and ferroelectric properties

被引:12
作者
Lather, Sushma [1 ]
Dalal, Jasvir [1 ]
Gupta, Anjli [1 ]
Singh, Sukhbir [2 ]
Singh, D. P. [3 ]
Dahiya, Sajjan [1 ]
Maan, A. S. [1 ]
Tripathi, Rahul [2 ,4 ]
Ohlan, Anil [1 ]
机构
[1] Maharshi Dayanand Univ, Dept Phys, Rohtak 124001, Haryana, India
[2] Maharshi Dayanand Univ, Univ Inst Engn & Technol, Rohtak 124001, Haryana, India
[3] Thapar Univ, Dept Phys, Patiala 147004, Punjab, India
[4] Chaudhary Bansi Lal Univ, Dept Phys, Bhiwani 127021, India
关键词
Multiferroics; Ball milling; Nanocomposites; Magnetic properties; Dielectric properties; PHASE-TRANSITION; GRAIN-SIZE; BEHAVIOR; FERRITE; CERAMICS;
D O I
10.1016/j.ceramint.2018.11.195
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structural, dielectric, ferroelectric and magnetoelectric (ME) properties of multiferroic [PbTiO3-Ni0.5Co0.5Fe2O4] (PT-NCF) composites have been discussed at room temperature. The uniformly distributed two-phase composites of PbTiO3 (ferroelectric) dispersed into nano-sized Ni0.5Co0.5Fe2O4 (ferromagnetic) of different particle size were synthesized by employing high energy ball milling for 12, 24 and 48 h respectively. The phase and morphology of composites were confirmed by XRD and SEM analysis respectively. The dielectric properties were determined at different frequencies (i.e. from 1 kHz to 1 MHz) and it is observed that the dielectric constant and ferroelectric transition temperature (T-C) decreases with particle size. Further, the ferroelectric behavior of the composites was discussed at room temperature by examining the P-E loops. The magnetic and magneto-electric measurements were performed to analyze the effect of particle size on ferromagnetic and magneto-electric properties of PT-NCF composites. The coexistence of ferroelectric and ferromagnetic properties in composites with strong ME coupling is essential for a good multiferroic composites material and its applications.
引用
收藏
页码:4957 / 4963
页数:7
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