Oxygen-plasma processed Spiro-OMeTAD toward high performance for perovskite solar cell

被引：24

作者：

Kim, Dong In ^{[1
]}

Lee, Ji Won ^{[1
,2
]}

Jeong, Rak Hyun ^{[1
,2
]}

Nam, Sang-Hun ^{[2
]}

Hwang, Ki-Hwan ^{[1
,2
]}

Boo, Jin-Hyo ^{[1
,2
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Inst Basic Sci, Suwon 440746, South Korea

来源：

SURFACE & COATINGS TECHNOLOGY | 2019年 / 357卷

基金：

新加坡国家研究基金会;

关键词：

Oxygen plasma; Perovskite solar cell; Aging effect; Plasma treatment; HOLE-TRANSPORTING MATERIALS; EFFICIENCY;

D O I：

10.1016/j.surfcoat.2018.09.072

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Efficient perovskite solar cell was achieved using a small hole transport material, Spiro-OMeTAD, after oxygen plasma treatment. It was demonstrated that the plasma treatment of hole transport layer for the solids state perovskite solar cell was enhanced power conversion efficiency. Reason for enhancing the cell performance of solar cell was good match of homo energy level between perovskite and Spiro-OMeTAD. It leads to transfer well hole carrier at Active/HTL interface. This study obtained highly improved performance by a current density of 25.4 mA/cm(2), an open-circuit voltage of 1.02 V, and a fill factor of 60.2%, which resulted showed above 15% of cell efficiency.

引用

页码：189 / 194

页数：6

共 50 条

[31] Solvent Engineering of a Dopant-Free Spiro-OMeTAD Hole-Transport Layer for Centimeter-Scale Perovskite Solar Cells with High Efficiency and Thermal Stability [J].

Hu, Min ;

Wu, Xuelian ;

Tan, Wen Liang ;

Tan, Boer ;

Scully, Andrew D. ;

Ding, Lei ;

Zhou, Cai ;

Xiong, Yuli ;

Huang, Fuzhi ;

Simonov, Alexandr N. ;

Bach, Udo ;

Cheng, Yi-Bing ;

Wang, Shengxiang ;

Lu, Jianfeng .

ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (07) :8260-8270

[32] Mixtures of Dopant-Free Spiro-OMeTAD and Water-Free PEDOT as a Passivating Hole Contact in Perovskite Solar Cells [J].

Kegelmann, Lukas ;

Tockhorn, Philipp ;

Wolff, Christian M. ;

Marquez, Jose A. ;

Caicedo-Davila, Sebastian ;

Korte, Lars ;

Unold, Thomas ;

Loevenich, Wilfried ;

Neher, Dieter ;

Rech, Bernd ;

Albrecht, Steve .

ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (09) :9172-9181

[33] Investigation on the Mechanism of Radical Intermediate Formation and Moderate Oxidation of Spiro-OMeTAD by the Synergistic Effect of Multisubstituted Polyoxometalates in Perovskite Solar Cells [J].

Hu, Boyuan ;

Zhang, Jian ;

Yang, Yulin ;

Wang, Jiaqi ;

Wang, Wei ;

Li, Jiao ;

Liu, Shihui ;

Xia, Debin ;

Lin, Kaifeng ;

Dong, Yayu ;

Fan, Ruiqing .

ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (15) :17610-17620

[34] Facile and Low-Cost Design Alternative of Spiro-OMeTAD as p-Type Semiconductor for Efficient Perovskite Solar Cells [J].

Daskeviciute, Sarune ;

Zhang, Yi ;

Daskeviciene, Maryte ;

Rakstys, Kasparas ;

Petrulevicius, Julius ;

Jankauskas, Vygintas ;

Getautis, Vytautas ;

Nazeeruddin, Mohammad Khaja .

SOLAR RRL, 2025, 9 (08)

[35] Room temperature deposition of IWO electrodes on Spiro-OMeTAD without buffer layers for Semi-transparent perovskite solar cells [J].

Song, Chao ;

Yan, Zhu ;

Zhang, Rujie ;

Zhang, Liping ;

Du, Weijie ;

Liu, Zhengxin ;

Zhang, Yiwen .

MATERIALS LETTERS, 2023, 347

[36] Interfacial versus Bulk Properties of Hole-Transporting Materials for Perovskite Solar Cells: Isomeric Triphenylamine-Based Enamines versus Spiro-OMeTAD [J].

Simokaitiene, Jurate ;

Cekaviciute, Monika ;

Baucyte, Kristina ;

Volyniuk, Dmytro ;

Durgaryan, Ranush ;

Molina, Desire ;

Yang, Bowen ;

Suo, Jiajia ;

Kim, YeonJu ;

da Silva Filho, Demetrio Antonio ;

Hagfeldt, Anders ;

Sini, Gjergji ;

Grazulevicius, Juozas, V .

ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (18) :21320-21330

[37] Design of two novel hole transport materials via replacing the core of spiro-OMeTAD with tetrathiafulvalene and tetraazafulvalene for application in perovskite solar cells [J].

Ashassi-Sorkhabi, Habib ;

Salehi-Abar, Parvin .

SOLAR ENERGY, 2018, 173 :132-138

[38] Effective Electron Blocking of CuPC-Doped Spiro-OMeTAD for Highly Efficient Inorganic-Organic Hybrid Perovskite Solar Cells [J].

Seo, Jangwon ;

Jeon, Nam Joong ;

Yang, Woon Seok ;

Shin, Hee-Won ;

Ahn, Tae Kyu ;

Lee, Jaemin ;

Noh, Jun Hong ;

Seok, Sang Il .

ADVANCED ENERGY MATERIALS, 2015, 5 (20)

[39] Evidence of Spiro-OMeTAD De-doping by tert-Butylpyridine Additive in Hole-Transporting Layers for Perovskite Solar Cells [J].

Lamberti, Francesco ;

Gatti, Teresa ;

Cescon, Enrico ;

Sorrentino, Roberto ;

Rizzo, Antonio ;

Menna, Enzo ;

Meneghesso, Gaudenzio ;

Meneghetti, Moreno ;

Petrozza, Annamaria ;

Franco, Lorenzo .

CHEM, 2019, 5 (07) :1806-1817

[40] Improved moisture resistance and interfacial recombination of perovskite solar cells by doping oleylamine in spiro-OMeTAD based hole-transport layer [J].

Liu, Shan ;

Wu, Shuyue ;

Xia, Pufeihong ;

Xie, Haipeng ;

Yuan, Xiaoming ;

Li, Youzhen ;

Kong, Deming ;

Huang, Han ;

Gao, Yongli ;

Zhou, Conghua .

APPLIED PHYSICS LETTERS, 2022, 120 (25)

← 1 2 3 4 5 →