Porous Nitrogen Rich Cadmium-Tetrazolate Based Metal Organic Framework (MOF) for H2 and CO2 Uptake

被引：52

作者：

Pachfule, Pradip ^{[1
]}

Banerjee, Rahul ^{[1
]}

机构：

[1] Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India

来源：

CRYSTAL GROWTH & DESIGN | 2011年 / 11卷 / 12期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; CARBON-DIOXIDE CAPTURE; COORDINATION POLYMERS; HYDROGEN STORAGE; GAS-ADSORPTION; SOLID-STATE; PORE-SIZE; DESIGN; IMIDAZOLATE;

D O I：

10.1021/cg201054f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly porous nitrogen rich metal organic framework [Cd-3(4-TP)(6)] (Cd-4TP-1) was synthesized solvothermally from the predesigned organic building block 4-tetrazole pyridine (4-TP) and Cd(II) as metal center using DMF as solvent. Cd-4TP-1 has a three-dimensional porous architecture where all the binding sites of Cd(II) are exclusively occupied by the nitrogen atoms from the mu(2)-tetrazolyl group or the pyridyl functionality of the 4-TP ligands. Cd-4TP-1 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 472.2 and 728.6 m(2)/g, respectively, and shows 1.1 wt % H-2 (77 K) and 2.7 mmol/g CO2 uptake (273 K).

引用

页码：5176 / 5181

页数：6

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